Calculate the heat change at $100^{\circ} \mathrm{C}$ for each of the following, and indicate whether heat was absorbed/released:
a. calories to vaporize $10.0 \mathrm{~g}$ of water
b. joules to vaporize $5.00 \mathrm{~g}$ of water
c. kilocalories to condense $8.0 \mathrm{~kg}$ of steam
d. kilojoules to condense $175 \mathrm{~g}$ of steam