Question

Consider a system of degenerate electrons at a low temperature in thermal equilibrium under the simultaneous influence of a density gradient and an electric field. (a) How is the chemical potential $\mu$ related to the electrostatic potential $\phi(x)$ and the Fermi energy $E_{\mathrm{F}}$ for such a system? (b) How does $E_{\mathrm{F}}$ depend on the electron density $n$ ? (c) From the condition for $\mu$ under thermal equilibrium and the considerations in (a) and (b), derive a relation between the electrical conductivity $\sigma$, the diffusion coefficient $D$ and the density of states at the Fermi surface for such a system.

   Consider a system of degenerate electrons at a low temperature in thermal equilibrium under the simultaneous influence of a density gradient and an electric field.
(a) How is the chemical potential $\mu$ related to the electrostatic potential $\phi(x)$ and the Fermi energy $E_{\mathrm{F}}$ for such a system?
(b) How does $E_{\mathrm{F}}$ depend on the electron density $n$ ?
(c) From the condition for $\mu$ under thermal equilibrium and the considerations in (a) and (b), derive a relation between the electrical conductivity $\sigma$, the diffusion coefficient $D$ and the density of states at the Fermi surface for such a system.
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Problems and Solutions on Thermodynamics and Statistical Mechanics
Problems and Solutions on Thermodynamics and Statistical Mechanics
U.S.T. of China… 1st Edition
Chapter 2, Problem 206 ↓

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In a system of degenerate electrons, the chemical potential $\mu$ can be expressed as: \[ \mu = E_{\mathrm{F}} - e\phi(x) \] where $e$ is the elementary charge. This equation indicates that the chemical potential is influenced by the electrostatic potential, which  Show more…

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Consider a system of degenerate electrons at a low temperature in thermal equilibrium under the simultaneous influence of a density gradient and an electric field. (a) How is the chemical potential $\mu$ related to the electrostatic potential $\phi(x)$ and the Fermi energy $E_{\mathrm{F}}$ for such a system? (b) How does $E_{\mathrm{F}}$ depend on the electron density $n$ ? (c) From the condition for $\mu$ under thermal equilibrium and the considerations in (a) and (b), derive a relation between the electrical conductivity $\sigma$, the diffusion coefficient $D$ and the density of states at the Fermi surface for such a system.
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