Each of the following is a reaction that occurs in the cells of the body. Identify each as exothermic or endothermic. (9.6)
a. Phosphocreatine $+\mathrm{H}_{2} \mathrm{O} \longrightarrow$ creatine $+\mathrm{P}_{\mathrm{i}}+42.7 \mathrm{~kJ}$
b. Fructose-6-phosphate $+\mathrm{P}_{\mathrm{i}}+16 \mathrm{~kJ} \longrightarrow$