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Rikhil M.
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Problem 1 Problem 2 Problem 3 Problem 4 Problem 5 Problem 6 Problem 7 Problem 8 Problem 9 Problem 10 Problem 11 Problem 12 Problem 13 Problem 14 Problem 15 Problem 16 Problem 17 Problem 18 Problem 19 Problem 20 Problem 21 Problem 22 Problem 23 Problem 24 Problem 25 Problem 26 Problem 27 Problem 28 Problem 29 Problem 30 Problem 31 Problem 32 Problem 33 Problem 34 Problem 35 Problem 36 Problem 37 Problem 38 Problem 39 Problem 40 Problem 41 Problem 42 Problem 43 Problem 44 Problem 45 Problem 46 Problem 47 Problem 48 Problem 49 Problem 50 Problem 51 Problem 52 Problem 53 Problem 54 Problem 55 Problem 56 Problem 57 Problem 58 Problem 59 Problem 60 Problem 61 Problem 62 Problem 63 Problem 64 Problem 65 Problem 66 Problem 67 Problem 68 Problem 69 Problem 70 Problem 71 Problem 72 Problem 73 Problem 74 Problem 75 Problem 76 Problem 77 Problem 78 Problem 79 Problem 80 Problem 81 Problem 82 Problem 83 Problem 84 Problem 85 Problem 86 Problem 87 Problem 88 Problem 89 Problem 90 Problem 91 Problem 92 Problem 93 Problem 94 Problem 95 Problem 96 Problem 97 Problem 98 Problem 99 Problem 100 Problem 101

Problem 32 Easy Difficulty

Explain how to recognize the conditions under which changes in pressure would affect systems at equilibrium.

Answer

In the container, the pressure is caused due to gas molecules which are in continuous motion and hence keep hitting the walls. The pressure experienced will be directly proportional to number of molecules. When the reaction is involving different number of moles of gaseous molecules on the reactant and product side, change in pressure will lead to affect the system at equilibrium. If for a reaction gas molecules of reactant is more than that of product side, then on increasing the pressure equilibrium will shift to the product side where gas molecules are less in number. For the reactions having more number of gas molecules on the reactant side, the increase in pressure will move the equilibrium in forward direction.

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Chemistry 102

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Chapter 13

Fundamental Equilibrium Concepts

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Problem 91
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Problem 101

Video Transcript

everyone, this is Ricky. And today we're gonna be working on a problem 32. And so be be explaining how to recognize conditions under which changes in pressure would effect would affect systems at equilibrium. So pressure, um, is caused by molecules bouncing against the walls of the container and against each other. And so when we have a system that has, for example, maybe two moles of gas on the left and five moles of gas all right, and we increase pressure, we're going to shift equilibrium to the left because of the shot liaise principle, um, saying that a system will try to make a rebound when there's a external force applied. And so in this case, were increasing pressure. So the way that we would decrease pressure is to shift to the left. And so, um, pressure has a difference on equilibrium when we have different numbers of moles of gas and the products of the reactions lips. But he was helpful. See, on the next one

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Paul Flowers, Klaus Theopold, Richard Langley, William R. Robinson

Chemistry

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