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For an equilibrium involving gaseous substances, what effect, in general terms, is realized when the volume of the system is decreased?
When the volume of the system is decreased, the pressure will increase. The system will try to minimize the pressure by forming less gaseous species. Hence, the equilibrium shifts to the direction that contains less number of moles of gases.
Chemistry 102
Chapter 17
Equilibrium
Section 7
Le Chatelier’s Principle
Chemical Equilibrium
University of Central Florida
Drexel University
University of Kentucky
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So this question asked, What is the effect of decreasing the volume on a gashes Equilibrium? The way you want to think about this is if we decreased of all you that is going to cause the total pressure to increase says pressure and volume are inversely related, according to PV equals NRT now, because the total pressure increases now, the equilibrium is gonna want to decrease the pressure back down. Days of the equal. A room wants to shift to decrease the pressure. John of the system, right? And when I say the total pressure increases, that means the pressure of all the gashes species of increased. All right. So in order to decrease the pressure, the only thing we can do by shifting the equilibrium is to shift to a side with less moles of guests. Because if you think about what pressure is and keep vehicles and our teeth by the less walls of gas we have in the container, the lower the pressure. And so that's the way you want to think about it in terms of value and what happens to the shift of the equilibrium. Now, when I say less most of gas, we are looking at the Stoke your metric coefficients of all the gashes species on those size of chemical immigration I and it's only the ones for the guests.
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