For each of the following solutions the mass of solute is given, followed by the total volume of solution prepared. Calculate the molarity.
a. $321 \mathrm{g}$ of $\mathrm{CaCl}_{2} ; 1.45 \mathrm{L}$
b. $4.21 \mathrm{mg}$ of $\mathrm{NaCl} ; 1.65 \mathrm{mL}$
c. $6.45 \mathrm{g} \mathrm{KBr} ; 125 \mathrm{mL}$
d. $62.5 \mathrm{g} \mathrm{NH}_{4} \mathrm{NO}_{3} ; 7.25 \mathrm{L}$