Question

For ideal solutions, the volumes are additive. This means that if 5 mL of A and 5 mL of B form an ideal solution, the volume of the solution is 10 mL . Provide a molecular interpretation for this observation. When 500 mL of ethanol $\left(\mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}\right)$ are mixed with 500 mL of water, the final volume is less than 1000 mL . Why?

   For ideal solutions, the volumes are additive. This means that if 5 mL of A and 5 mL of B form an ideal solution, the volume of the solution is 10 mL . Provide a molecular interpretation for this observation. When 500 mL of ethanol $\left(\mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}\right)$ are mixed with 500 mL of water, the final volume is less than 1000 mL . Why?
 
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Chemistry
Chemistry
Raymond Chang, Jason… 14th Edition
Chapter 12, Problem 117 ↓
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For ideal solutions, the volumes are additive. This means that if 5 mL of A and 5 mL of B form an ideal solution, the volume of the solution is 10 mL . Provide a molecular interpretation for this observation. When 500 mL of ethanol $\left(\mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}\right)$ are mixed with 500 mL of water, the final volume is less than 1000 mL . Why?
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For ideal solutions, the volumes are additive. This means that if $5 \mathrm{mL}$ of $\mathrm{A}$ and $5 \mathrm{mL}$ of $\mathrm{B}$ form an ideal solution, the volume of the solution is $10 \mathrm{mL}$ Provide a molecular interpretation for this observation. When $500 \mathrm{mL}$ of ethanol $\left(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}\right)$ are mixed with $500 \mathrm{mL}$ of water, the final volume is less than $1000 \mathrm{mL} .$ Why?

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When 50 $\mathrm{mL}$ of liquid water at $25^{\circ} \mathrm{C}$ is added to 50 $\mathrm{mL}$ of ethanol (ethyl alcohol), also at $25^{\circ}$ ' $\mathrm{C},$ the combined volume of the mixture is considerably less than 100 $\mathrm{mL}$ . Give a possible explanation.

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30. When $50 \mathrm{~mL}$ of liquid water at 25 " ${ }^{\circ} \mathrm{C}$ is added to $50 \mathrm{~mL}$ of ethanol (ethyl alcohol), also at 25 ${ }^{\circ} \mathrm{C}$ , the combined volume of the mixture is considerably less than $100 \mathrm{~mL}$. Give a possible explanation.

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Transcript

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00:01 An ideal solution, when we mix two components, they don't really perturb the system.
00:13 In a sense that, let's imagine that we have a solution right here, it's pure, and we have another solution that we're about to mix with that one, where we have other component, okay? and, you know, inside the liquid there are some intermolecular attractions going on.
00:37 They feel each other.
00:40 Okay.
00:41 And they have an average distance, right? now, once you mix those two solutions, if this is an ideal solution, what's going to happen is that the, say, the green doesn't really care much that you now introduced red stuff in.
01:01 There.
01:02 It will still behave the same, keeping the same distance, interacting with about the same strength.
01:09 Okay.
01:10 So nothing will really change.
01:11 So that's the case of an ideal solution.
01:15 And so in order to have an ideal solution, the molecules have to be similar enough that the size and the strength of the interaction between the molecules is about the same...
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