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Problem 58

For the gaseous reaction of carbon monoxide and chlorine to form phosgene $\left(\mathrm{COCl}_{2}\right) :$
(a) Calculate $\Delta S^{\circ}$ at 298 $\mathrm{K}\left(\Delta H^{\circ}=-220 . \mathrm{kJ} / \mathrm{mol} \text { and } \Delta G^{\circ}=\right.$ $-206 \mathrm{kJ} / \mathrm{mol}$ ).
(b) Assuming that $\Delta S^{\circ}$ and $\Delta H^{\circ}$ change little with temperature, calculate $\Delta G^{\circ}$ at $450 . \mathrm{K}$ .

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Chapter 20
Thermodynamics: Entropy, Free Energy, and the Direction of Chemical Reactions
CHEMISTRY: The Molecular Nature of Matter and Change 2016

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