Question
Give a qualitative argument based on the kinetic theory of gases to show that the coefficient of viscosity of a classical gas is independent of the pressure at constant temperature.
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Viscosity is a measure of a fluid's resistance to flow. In the context of gases, it describes how easily gas layers slide past one another when a shear force is applied. Show more…
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(A): The viscosity of an ideal gas is independent of pressure at constant temperature. (R): As the pressure is increased, the effect of the increase in number density of molecules in compensated by a proportionate decrease in the mean free path.
Derive the ideal gas law without the assumption of no intermolecule collisions. To simplify this calculation, make the radical assumption that the $x$ -components of the velocities of all molecules have the same magnitude; that is, assume that all molecules have the same $\left|v_{x}\right|$, with half the molecules moving to the right and the other half moving to the left; make similar assumptions for $y$ - and $z$ -directions. Consider a gas of molecules with number density $n$ in a cubical container, and consider only those molecules that are within a short distance $\Delta x$ of one wall of the container where $\Delta x \ll \lambda$, the mean free path. At any instant, half of those molecules are heading toward the wall and will collide with the wall in an average time $\Delta t$, where $\Delta x / \Delta t=\left|v_{x}\right| .$ Proceed to compute the average force on the the wall due to molecular collisions, and then deduce the ideal gas law.
Atoms
The Mean Free Path and Diffusion
Show that $\left(\partial C_{V} / \partial V\right)_{T}=0$ for an ideal gas, a gas follow$\operatorname{ing} P=n R T /(V-n b),$ and a van der Waals gas.
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