Give the structures of the two tertiary amines that are...

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Key Concepts

Tertiary Amines

Tertiary amines are a class of amines in which the nitrogen atom is bonded to three alkyl or aryl substituents and contains no hydrogen atoms. This lack of N–H bonds distinguishes them from primary and secondary amines, and it influences their basicity, steric properties, and overall reactivity in organic synthesis.

Constitutional Isomerism

Constitutional isomers are compounds that share the same overall molecular formula but differ in the connectivity of their atoms. In organic chemistry, this means that even though two compounds may have the same number of each type of atom, the way those atoms are arranged can produce distinctly different molecules with unique physical and chemical properties.

Alkyl Group Distribution in Amine Isomers

When forming amine isomers from a fixed molecular formula, the total number of carbon atoms must be partitioned among the substituent groups attached to the nitrogen. Different partitions, such as dividing the carbon count as 1,1,3 versus 1,2,2, lead to different structural arrangements. This distribution is central to understanding how compounds with the same formula can exhibit diverse structures and reactivities.

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