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Solutions of hydrogen in palladium may be formed …

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Problem 7 Easy Difficulty

Heat is released when some solutions form; heat is absorbed when other solutions form. Provide a molecular explanation for the difference between these two types of spontaneous processes.

Answer

In case of solution which release heat, sum of bond energies of the reactants is less than sum of
bond energies of the product. Since there is a surplus of energy, it is released in form of heat.
In case of solution which absorb heat, sum of bond energies of the reactants is greater than sum
of bond energies of the product. Since there is a dearth of energy, it is absorbed in form of heat.

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01:07

Aadit S.

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Chemistry 102

Chemistry

Chapter 11

Solutions and Colloids

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Video Transcript

If heat is absorbed during the formation of a solution, we can provide a molecular explanation based upon the types of inter molecular forces found between the solute and solvent with heat being absorbed, then energy is required for the process to occur. It always requires more energy to pull apart molecules that are strongly held together with strong inter molecular forces than it is to pull apart molecules with weak inter molecular forces. So if heat is absorbed, this suggests that the inter molecular forces of the solution are weaker than the inter molecular forces of the solute and solvent separate. The heat then is what is needed in order to pull apart the salute salute or to overcome the salute salute interaction and the solvent solvent interaction so that the weaker solute solvent interaction can occur essentially when heat is absorbed, weaker interactions are formed. If heat is released, then we are going to a lower energy state. A lower energy state corresponds to stronger forces of attraction. So when he is released the total inter molecular forces of the solution and the salt of the solution with the solute and solvent mixed are stronger than the total inter molecular forces of the separate, pure solute and solvent. These stronger forces result in the release of energy as heat.

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