Question
How will the rate of each of the following $S_{N} 2$ reactions change if it is carried out in a more polar solvent?
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In reactions a) and b), the reactants are charged species, while in reaction c), the reactants are neutral but the transition state is charged. Show more…
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How will the rate of each of the following $S_{N} 2$ reactions change if the polarity of a protic polar solvent is increased?
How will the rate of each of the following $\mathrm{S}_{\mathrm{N}} 2$ reactions change if it is carried out in a more polar solvent? a. $\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{Br}+\mathrm{HO}^{-} \longrightarrow \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH}+\mathrm{Br}^{-}$ b. c. $\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{I}+\mathrm{NH}_{3} \longrightarrow \mathrm{CH}_{3} \mathrm{CH}_{2}+\mathrm{NH}_{3} \mathrm{I}^{-}$
For the reaction of 2-bromopentane with sodium methoxide, what would the effect be of changing the solvent from DMSO ((CH3)2S=O) to methanol? The rate would decrease because SN2 reactions favor a polar aprotic solvent. The rate would increase because SN1 reactions favor a polar protic solvent. The rate would decrease because SN1 reactions favor a polar aprotic solvent. The rate would increase because SN2 reactions favor a polar protic solvent.
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