Limestone, $\mathrm{CaCO}_{3}$, is a water-insoluble material, whereas $\mathrm{Ca}\left(\mathrm{HCO}_{3}\right)_{2}$ is soluble. Caves are formed when rainwater containing dissolved $\mathrm{CO}_{2}$ passes over limestone for long periods of time. Write a chemical equation for the acid-base reaction.