Question

Often the determination of the molar mass of a compound by osmotic pressure measurement is carried out at several different concentrations to get a more reliable average value. From the following data for the osmotic pressure of poly(methyl methacrylate) in toluene at $25^{\circ} \mathrm{C}$, determine graphically the molar mass of the polymer. [Hint: Rearrange Equation (12.8) so that $\pi$ is expressed in terms of $c$, which is the number of grams of the solute per liter of solution.] $$ \begin{array}{cccccc} \pi(\mathrm{atm}) & 8.40 \times & 1.72 \times & 2.52 \times & 3.23 \times & 7.75 \times \\ & 10^{-4} & 10^{-3} & 10^{-3} & 10^{-3} & 10^{-3} \\ c(\mathrm{~g} / \mathrm{L}) & 8.10 & 12.31 & 15.00 & 18.17 & 28.05 \end{array} $$

   Often the determination of the molar mass of a compound by osmotic pressure measurement is carried out at several different concentrations to get a more reliable average value. From the following data for the osmotic pressure of poly(methyl methacrylate) in toluene at $25^{\circ} \mathrm{C}$, determine graphically the molar mass of the polymer. [Hint: Rearrange Equation (12.8) so that $\pi$ is expressed in terms of $c$, which is the number of grams of the solute per liter of solution.]
$$
\begin{array}{cccccc}
\pi(\mathrm{atm}) & 8.40 \times & 1.72 \times & 2.52 \times & 3.23 \times & 7.75 \times \\
& 10^{-4} & 10^{-3} & 10^{-3} & 10^{-3} & 10^{-3} \\
c(\mathrm{~g} / \mathrm{L}) & 8.10 & 12.31 & 15.00 & 18.17 & 28.05
\end{array}
$$
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Chemistry
Chemistry
Raymond Chang, Jason… 14th Edition
Chapter 12, Problem 139 ↓
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Often the determination of the molar mass of a compound by osmotic pressure measurement is carried out at several different concentrations to get a more reliable average value. From the following data for the osmotic pressure of poly(methyl methacrylate) in toluene at $25^{\circ} \mathrm{C}$, determine graphically the molar mass of the polymer. [Hint: Rearrange Equation (12.8) so that $\pi$ is expressed in terms of $c$, which is the number of grams of the solute per liter of solution.] $$ \begin{array}{cccccc} \pi(\mathrm{atm}) & 8.40 \times & 1.72 \times & 2.52 \times & 3.23 \times & 7.75 \times \\ & 10^{-4} & 10^{-3} & 10^{-3} & 10^{-3} & 10^{-3} \\ c(\mathrm{~g} / \mathrm{L}) & 8.10 & 12.31 & 15.00 & 18.17 & 28.05 \end{array} $$
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Transcript

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00:01 Okay, we're asked to consider some osmotic pressure calculations, and we're told that osmotic pressure is measured at several different concentrations to get a more reliable average value.
00:15 And we are looking at data for polymethymethyl metacrylate in tullewine at 25 degrees c.
00:27 From this, we're asked to graphically determine the molar mass of the polymer.
00:32 It tells us to rearrange an equation so that pi is expressed in terms of c, which is the number of grams per liter.
00:42 Okay, let's see here.
00:49 So let's go ahead and see if we can get a graph here.
00:55 This looks like a, what does it say? the pi is expressed in terms of c.
01:23 Okay, and when we plug these data in, we're getting a slope.
01:42 Let me look here...
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