Question
Prove that the internal energy is a function of temperature only, that is, $u=u(T)$ for(a) an incompressible substance.(b) an ideal gas.
Step 1
The internal energy (u) of a substance depends on its temperature (T), pressure (P), and volume (V). Since the volume is constant, we can write the differential of internal energy as: du = (∂u/∂T)_V dT + (∂u/∂P)_V dP Now, we know that the heat capacity at Show more…
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Key Concepts
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Show that the enthalpy of an ideal gas is a function of temperature only and that for an incompressible substance it also depends on pressure.
Derive an expression giving (a) the internal energy of a substance relative to that of its ideal gas model at the same temperature: $\left[u(T, v)-u^{*}(T)\right]$. (b) the entropy of a substance relative to that of its ideal gas model at the same temperature and specific volume: $\left[s(T, v)-s^{*}(T, v)\right] .$
Thermodynamic Relations
Problems: Developing Engineering Skills
You have a gas that follows the ideal gas equation (Pv = RT). Assuming that there is Thermodynamic equilibrium at all states. Show that if the temperature is being hold constant, the internal energy cannot be a function of: a) v b) P
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