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Problem

The lattice energy of CsF is -744 kJ>mol whereas …

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Eugene S.
University of Minnesota - Twin Cities

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Problem 92 Easy Difficulty

Rubidium iodide has a lattice energy of -617 kJ>mol, while potassium bromide has a lattice energy of -671 kJ>mol. Why is the lattice energy of potassium bromide more exothermic than the lattice energy of rubidium iodide?

Answer

The lattice energy of potassium bromide is more exothermic than that of Rubidium iodide due to
the difference in sizes of cations and anions. Rubidium is a larger cation than potassium and
iodide ion is larger than bromide ion. This increases the distance between the charges in
Rubidium iodide.
Potential energy decreases as distance between the charges increases according to Coulomb's
law. So larger molecules have lower potential energy. This causes lower lattice energy for
Rubidium iodide.

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Video Transcript

So this problem asks, Why is thie lattice energy of potassium bromide more extra thermic than rubidium iodide? So we start with rubidium iodide, which has a lattice energy of negative six seventeen killer Jules per mall, and potassium bromide, which has a lattice energy of negative six seventy one Kila Jules per mall. And so the reason that potassium bromide is mohr XO thermic is because lattice energy is inversely proportional to atomic radius. So a larger atomic radius means that it's less XO thermic for lattice energy. And so, since K B R has a smaller atomic radius, it's going to have a mohr XO thermic lattice energy.

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