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Rubidium iodide has a lattice energy of -617 kJ>mol, while potassium bromide has a lattice energy of -671 kJ>mol. Why is the lattice energy of potassium bromide more exothermic than the lattice energy of rubidium iodide?
The lattice energy of potassium bromide is more exothermic than that of Rubidium iodide due tothe difference in sizes of cations and anions. Rubidium is a larger cation than potassium andiodide ion is larger than bromide ion. This increases the distance between the charges inRubidium iodide.Potential energy decreases as distance between the charges increases according to Coulomb'slaw. So larger molecules have lower potential energy. This causes lower lattice energy forRubidium iodide.
Chemistry 102
Chemistry 101
Chapter 9
Thermochemistry
Thermodynamics
Chemical reactions and Stoichiometry
Carleton College
University of Central Florida
Brown University
University of Toronto
Lectures
00:42
In thermodynamics, the zer…
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Rubidium iodide has a latt…
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So this problem asks, Why is thie lattice energy of potassium bromide more extra thermic than rubidium iodide? So we start with rubidium iodide, which has a lattice energy of negative six seventeen killer Jules per mall, and potassium bromide, which has a lattice energy of negative six seventy one Kila Jules per mall. And so the reason that potassium bromide is mohr XO thermic is because lattice energy is inversely proportional to atomic radius. So a larger atomic radius means that it's less XO thermic for lattice energy. And so, since K B R has a smaller atomic radius, it's going to have a mohr XO thermic lattice energy.
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