The molar mass of carbon (C) is 12.01 g/mol, hydrogen (H) is 1.01 g/mol, and oxygen (O) is 16.00 g/mol. Therefore, the molar mass of sucrose is $12(12.01 \, \text{g/mol}) + 22(1.01 \, \text{g/mol}) + 11(16.00 \, \text{g/mol}) = 342.29 \, \text{g/mol}$.
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