Suggest reagents (a-h) for the following transformations. More than one step may be required for each transformation. (The relative stereochemistry of the products is shown, not the absolute stereochemistry.) (Sections $21.3$ and 21.4)

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Chemistry $^{3}$ : Introducing inorganic, organic and physical chemistry

Chapter 21

Alkenes and alkynes: electrophilic addition and pericyclic reactions

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So we have to get the regions for the products. And following reactions and an eighth rage, we're starting with metal cycle vaccine. So the Ian Plan, we've been now keen and the first one we want to get we have and we have, um we have seen edition of the alcohols. So this is characteristic of reacting peroxide with plasmodium tetroxide. This will give a sin edition, and obviously the method is still here, So just anti to the alcohols. So in the second one, we have with anti edition of grooming and the L h. So this is similar to the challenge Nature action when we did br two or C L two with CCL four, except in the second step when we have the pox, I'd like structure. So if you have this and the second step, we're gonna react water instead of burning with it's gonna attack this carbon and open up the ring. So before this is Jeremy in, it's gonna be word of this thing. So it's, um br two with water. Give me a scanty edition and, um, the next one is Wait, wait. I scared day. Ah, So we have sent the bomb or column competition of the alcohol and a metal. So you can use either oxy, Mercure ation or dehydration reaction. Excuse hydration. That'll give us, um, more comic competition. Actually, it's for B two. C was the anti edition of Berman and the and the water. Just be just say if her d we have with anti McCollum competition of the alcohol. This is hydro generation. Here's the method. And uhh Did I lost stable position. So this is gonna be bh three with th f over peroxide and hydroxide. So for E, we have, uh, anti edition of the alcohols. So in a way, that's in addition. Okay, So reacting this with a proxy acid like EMC PBA over you hide uranium iron will give us anti edition and then an f we have a 1234567 You have a seven carbon chain, the car bucks look ass at the end and a carbon city of Aachen. So we're starting with metal cycle vaccine. So in every treat a, um, a cyclic structure and a keen like psycho vaccine with potassium prove agony. It's going to break the double bond and each carbon here gets get, some will become a huge turn. But if there's any hydrogen is attached to these carbons, they're gonna be oxidized into car box stock acids. So it's pretty strong oxidizing agent, but because this carpenter here doesn't have any Hodgins, we have this group. The metal. Yeah, keen. And then obviously this Bonder here. So there's no hydrogen there, so we're not going to get a carb oxalic acid. We're gonna get you tune. So if this is carbon one, we have the key zone right here and then attached that as the methyl, which is over here. This is too three, 45 and 6 to 6 out of hydrogen. So it'll turn into a car box Silk acid, then just county over here. That's not a potassium for magnet And Fergie, we have the app oxide. So you're treating in our keen with em CPB A will give us the Gibson naproxen. Would that be a cyclic structure or just not keen? It's a proxy acid. And finally, for H given out ahead so we can treat this with, um, we can use the ozone license reaction treating this with, um oh three and zinc with acid. This was in like Isis. First step. The second step is zinc with or zinc over. You had uranium I on Hulu Plus, so it's similar to potassium permanganate, but it's not gonna oxidize the hydrogen. It's just going to leave an alga hood, so it's not as strong, but it's still gonna open the ring. So we're still gonna have a seven carbon ring, but instead of carbon stock assets in Alba Hood. But this carbon, so was a key tune, and it's pretty similar.

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