Question

The proton NMR spectral information shown in this problem is for a compound with formula $\mathrm{C}_{10} \mathrm{H}_{12} \mathrm{O}_2$. One proton, not shown, is a broad peak that appears at about $12.8 \mathrm{ppm}$. Expansions are shown for the protons absorbing in the region from 3.5 to $1.0 \mathrm{ppm}$. The monosubstituted benzene ring is shown at about $7.2 \mathrm{ppm}$ but is not expanded because it is uninteresting. The normal carbon-13 spectral results, including DEPT-135 and DEPT-90 results, are tabulated: TABLE CANT COPY Draw the structure of this compound and assign each of the protons in your structure. Explain why the interesting pattern is obtained between 2.50 and $2.75 \mathrm{ppm}$. Draw tree diagrams as part of your answer. DIAGRAM CANT COPY

   The proton NMR spectral information shown in this problem is for a compound with formula $\mathrm{C}_{10} \mathrm{H}_{12} \mathrm{O}_2$. One proton, not shown, is a broad peak that appears at about $12.8 \mathrm{ppm}$. Expansions are shown for the protons absorbing in the region from 3.5 to $1.0 \mathrm{ppm}$. The monosubstituted benzene ring is shown at about $7.2 \mathrm{ppm}$ but is not expanded because it is uninteresting. The normal carbon-13 spectral results, including DEPT-135 and DEPT-90 results, are tabulated:
TABLE CANT COPY
Draw the structure of this compound and assign each of the protons in your structure. Explain why the interesting pattern is obtained between 2.50 and $2.75 \mathrm{ppm}$. Draw tree diagrams as part of your answer.
DIAGRAM CANT COPY
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Introduction to Spectroscopy
Introduction to Spectroscopy
Donald L. Pavia,… 4th Edition
Chapter 5, Problem 19 ↓

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This indicates that the compound contains a total of 10 carbon atoms, 12 hydrogen atoms, and 2 oxygen atoms. The presence of 2 oxygen atoms suggests that there may be functional groups such as esters, acids, or alcohols.  Show more…

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The proton NMR spectral information shown in this problem is for a compound with formula $\mathrm{C}_{10} \mathrm{H}_{12} \mathrm{O}_2$. One proton, not shown, is a broad peak that appears at about $12.8 \mathrm{ppm}$. Expansions are shown for the protons absorbing in the region from 3.5 to $1.0 \mathrm{ppm}$. The monosubstituted benzene ring is shown at about $7.2 \mathrm{ppm}$ but is not expanded because it is uninteresting. The normal carbon-13 spectral results, including DEPT-135 and DEPT-90 results, are tabulated: TABLE CANT COPY Draw the structure of this compound and assign each of the protons in your structure. Explain why the interesting pattern is obtained between 2.50 and $2.75 \mathrm{ppm}$. Draw tree diagrams as part of your answer. DIAGRAM CANT COPY
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