The reaction $\mathrm{SO}_{2} \mathrm{Cl}_{2}(g) \longrightarrow \mathrm{SO}_{2}(g)+\mathrm{Cl}_{2}(g)$ is first order in $\mathrm{SO}_{2} \mathrm{Cl}_{2} .$ Using the following kinetic data, determine the magnitude and units of the first-order rate constant: