00:02
This is the answer to chapter 26, problem number 37 from the smith organic chemistry textbook.
00:10
This problem is describing a heck reaction that forms product e only and not the expected product f.
00:22
And we are asked to account for this by drawing a stepwise mechanism.
00:28
And then also to talk about the third.
00:32
Step, the stereochemistry of the third step of the mechanism.
00:38
Okay, so the first thing that's going to happen is going to be oxidative addition.
00:45
So i'm going to just abbreviate that as oa.
00:47
So the palladium will oxidatively add.
00:59
So the plating adds there.
01:04
The iodine is still there.
01:07
And then the two ligands.
01:16
Okay.
01:16
So they're going to look like that.
01:20
So then the cyclohexene comes in there.
01:31
Okay.
01:32
And so we get a sin addition as our second step.
01:45
So now the palladium is here.
01:53
Got to move it down.
01:59
Okay.
02:00
So the palladium is here with its two ligands and the iodine.
02:11
Okay.
02:13
And the fennel ring will be here.
02:28
And so now the third step that's going to happen here is going to be a sin elimination.
02:41
So actually going to move this over a little bit...