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Problem 97

Consider the reaction $\mathrm{X}_{2}(g) \longrig…

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Problem 96

The values of $\Delta G_{\mathrm{f}}^{\circ}$ for the hydrogen halides become less negative with increasing atomic number. The $\Delta G_{\mathrm{f}}^{\circ}$ of HI is slightly positive. However, the trend in $\Delta S_{\mathrm{f}}^{\circ}$ is to become more positive with increasing atomic number. Explain.

Answer

with increasing atomic number $\Delta S_{\mathrm{f}}^{0}$ is more positive.


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