Question
There is no direct test for the detection of which of the following when present in an organic compound?(a) Cl(b) O(c) S(d) N
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The question asks which element among chlorine (Cl), oxygen (O), sulfur (S), and nitrogen (N) does not have a direct test for detection when present in an organic compound. Show more…
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An organic compound contains $\mathrm{C}, \mathrm{H}, \mathrm{N}, \mathrm{S}$ and $\mathrm{Cl}$. For the detection of chlorine, the sodium extarct of the compound is first heated with a few drops of concentrated $\mathrm{HNO}_{3}$ and then $\mathrm{AgNO}_{3}$ is added to get a white ppt. of $\mathrm{AgCl}$. The digestion with $\mathrm{HNO}_{3}$ before the addition of $\mathrm{AgNO}_{3}$ is (a) to prevent the formation of $\mathrm{NO}_{2}$ (b) to create a common ion effect (c) to convert $\mathrm{CN}$ - and $\mathrm{S}^{2-}$ to volatile $\mathrm{HCN}$ and $\mathrm{H}_{2} \mathrm{~S}$, or else they will interfere with the test forming $\mathrm{AgCN}$ or $\mathrm{Ag}_{2} \mathrm{~S}$ (d) to prevent the hydrolysis of $\mathrm{NaCN}$ and $\mathrm{Na}_{2} \mathrm{~S}$
Practical Organic Chemistry
Level I
The Beilstein test for organic compounds is used to detect (a) nitrogen (b) sulphur (c) carbon (d) halogens
An organic compound contains $\mathrm{C}, \mathrm{H}, \mathrm{N}, \mathrm{S}$ and Cl. for the detection of chlorine, the sodium extract of the compound is first heated with a few drops of concentrated $\mathrm{HNO}_{3}$ and then $\mathrm{AgNO}_{3}$ is added to get a white precipitate of AgCl. The digestion with $\mathrm{HNO}_{3}$ before the addition of $\mathrm{AgNO}_{3}$ is (a) To create a common ion effect. (b) To prevent the formation of $\mathrm{NO}_{2}$ (c) To prevent the hydrolysis of $\mathrm{NaCN}$ and $\mathrm{Na}_{2} \mathrm{~S}$. (d) To convert $\mathrm{CN}^{-}$ and $\mathrm{S}^{2-}$ volatite $\mathrm{HCN}$ and $\mathrm{H}_{2} \mathrm{~S}$, or else they will interfere with the test forming $\mathrm{AgCN}$ or $\mathrm{Ag}_{2} \mathrm{~S}$.
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