Under the same conditions, how many $\mathrm{mL}$ of $1 \mathrm{M}$ KOII and $0.5 \mathrm{M} \mathrm{II}_{2} \mathrm{SO}_{4}$ solutions respectively when mixed for a total volume of $100 \mathrm{~mL}$ produce the highest rise in temperature?
(1) $67: 33$
(2) $33: 67$
(3) $40: 60$
(4) $50: 50$