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Problem 1 Problem 2 Problem 3 Problem 4 Problem 5 Problem 6 Problem 7 Problem 8 Problem 9 Problem 10 Problem 11 Problem 12 Problem 13 Problem 14 Problem 15 Problem 16 Problem 17 Problem 18 Problem 19 Problem 20 Problem 21 Problem 22 Problem 23 Problem 24 Problem 25 Problem 26 Problem 27 Problem 28 Problem 29 Problem 30 Problem 31 Problem 32 Problem 33 Problem 34 Problem 35 Problem 36 Problem 37 Problem 38 Problem 39 Problem 40 Problem 41 Problem 42 Problem 43 Problem 44 Problem 45 Problem 46 Problem 47 Problem 48 Problem 49 Problem 50 Problem 51 Problem 52 Problem 53 Problem 54 Problem 55 Problem 56 Problem 57 Problem 58 Problem 59 Problem 60 Problem 61 Problem 62 Problem 63 Problem 64 Problem 65 Problem 66 Problem 67 Problem 68 Problem 69 Problem 70 Problem 71 Problem 72 Problem 73 Problem 74 Problem 75 Problem 76 Problem 77 Problem 78 Problem 79 Problem 80 Problem 81 Problem 82 Problem 83 Problem 84 Problem 85 Problem 86 Problem 87 Problem 88 Problem 89 Problem 90 Problem 91 Problem 92 Problem 93 Problem 94 Problem 95 Problem 96 Problem 97 Problem 98 Problem 99 Problem 100 Problem 101 Problem 102 Problem 103 Problem 104 Problem 105 Problem 106 Problem 107 Problem 108 Problem 109 Problem 110 Problem 111 Problem 112 Problem 113 Problem 114 Problem 115 Problem 116

Problem 116 Easy Difficulty

Use the Molecule Shape simulator (http://openstaxcollege.org/l/16MolecShape) to explore real
molecules. On the Real Molecules tab, select “model” mode and S2O. What is the model bond angle? Explain whether the “real” bond angle should be larger or smaller than the ideal model angle.

Answer

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Chemistry 101
Chemistry

Chapter 7

Chemical Bonding and Molecular Geometry

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Video Transcript

Hi there. This question asks us to look at it. Says s 20 in the model. However, the simulator does not have an s 20 but it does have an s 02 So I'm going to solve this for s 02 realizing that even if there were an s 20 it's going to be the same result because sulfur and oxygen are both groups Six elements so s 02 and this fictitious as 20 would end up looking the same. Eso I'm proceeding with eso to the model for this shows the sulfur double bonded to an oxygen single bonded to an oxygen with a lone pair. So as we look at this in the model, look at the molecular or look at the electron geometry structure that we're getting. We're getting three things lone pair of electrons, a double bond and a single bond attached to that central Adam. Therefore, we have the tribunal player Nothing electron geometry. So if we think about taking a circle and dividing it into thirds Hey, that gives us a bond angle of 120 degrees between these two bonds here on this molecule However, we realize that in riel molecules, these lone pairs up here actually exert more repulsion than bonded electrons. So this lone pair up here is pushing these guys farther away from it, which results in pushing them closer together. That's going to reduce that bond angle so that bond angle is going to be less than 120 degrees in the rial molecule. And when we check on it, indeed, it ISS. It's recorded as 119 degrees in the simulation, right? So that's what you should have discovered by working with the simulation. Thank you so much for watching.

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Paul Flowers, Klaus Theopold, Richard Langley, William R. Robinson

Chemistry

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