Water initially at $200 \mathrm{kPa}$ and $300^{\circ} \mathrm{C}$ is contained in a piston-cylinder device fitted with stops. The water is allowed to cool at constant pressure until it exists as a saturated vapor and the piston rests on the stops. Then the water continues to cool until the pressure is $100 \mathrm{kPa}$. On the $T$ -u diagram, sketch, with respect to the saturation lines, the process curves passing through the initial, intermediate, and final states of the water. Label the $T, P,$ and $\cup$ values for end states on the process curves. Find the overall change in internal energy between the initial and final states per unit mass of water.