00:01
This question asks us to draw the product of each of these reactions, but before we start and want to do a quick recap of what a deals alder reaction looks like, because that's what all of these are.
00:11
They're all deals alder reactions.
00:13
So in the deals alder reaction, we have a dyeing.
00:17
This is the simplest dying, and then a dineophile.
00:20
Dying file can be a double or a triple bond, and then both of these can have any other sort of attachments on them.
00:27
But this is the simplest version.
00:28
So all that happens is this double bond.
00:31
Swings over here, this one swings over here, and this one swings back here.
00:36
And we always, always end up with this six -membered ring with a double bond left over on the dyene side.
00:43
So this is going to be the basis of each product.
00:46
So i'm going to draw all of our reactants to look more like this so it's easier to see.
00:50
So for part a, we have the same dyeing that i drew above, if you draw it in that form.
00:55
And then our dineophile is a triple bond in this case with some ketones.
01:01
Attached to it that look like this.
01:04
So here we're going to do the same thing.
01:07
This will swing here.
01:08
This will swing here.
01:09
This will swing here.
01:11
And so that six -membered ring that we had above, we have that double bond left over on the dying side always.
01:17
And then in this case, because our dineophile was a triple bond instead of a double bond, we have an extra pie bond over there.
01:23
So that ends up being a double bond as well.
01:26
And then we'll just throw those ketones that were on our dineophile right on that side of the ring.
01:32
There's our product for part a.
01:34
For part b, we have the same dyeing, and then our dineophile here is another triple bond with that cyanide group on it...