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What is the basis of Ziesel method for estimation of methoxy group?
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It is commonly found in organic compounds such as ethers and esters. Show more…
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The Zeisel method is an old analytical procedure for determining the number of methoxyl groups in a compound. A weighed amount of the compound is heated with concentrated HI, ether cleavage occurs, and the iodomethane product is distilled off and passed into an alcohol solution of AgNO $_{3}$, where it reacts to form a precipitate of silver iodide. The AgI is then collected and weighed, and the percentage of methoxyl groups in the sample is thereby determined. For example, $1.06 \mathrm{g}$ of vanillin, the material responsible for the characteristic odor of vanilla, yields $1.60 \mathrm{g}$ of AgI. If vanillin has a molecular weight of $152,$ how many methoxyl groups does it contain?
Determine if the following are electron-releasing or electron-withdrawing groups: Methyl 3-methoxybenzoate Methyl 4-methoxybenzoate
Ethyl bromide and methoxybenzene (shown below) have the same nominal molecular weights, displaying a significant peak at m/z 108. Regarding their molecular ions, what other features would allow the two compounds to be distinguished on the basis of their mass spectra? (FIGURE CANNOT COPY)
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