00:02
This is the answer to chapter 2, problem number 35, from the smith organic chemistry textbook.
00:10
And this problem asks us to draw the conjugate acid of each of these bronstead -lowary bases.
00:18
And so remember, by definition, a bronstead -lowary base is a molecule that can accept a proton.
00:26
And so essentially what we're going to do for each of these six is just add a proton.
00:31
I mean, it should be pretty apparent as to where that protons can add in many of these cases.
00:39
Actually, in just about all of them, there's really only one place the proton can add.
00:43
So, for example, in a, h2o is going to become h3o plus for b.
00:54
And you know what? i'm going to go ahead and put loan pairs in because it may be helpful if you're still not entirely certain.
01:03
About some of this.
01:05
So i'll put loan pairs in very quickly.
01:18
Okay.
01:19
So there we go.
01:20
So that might help you decide where to where to put the hydrogen.
01:24
So for b it's going to go on the nitrogen.
01:28
So nh2 minus is going to become nh3 uncharged and now with only a single loan pair on the nitrogen.
01:40
H .c .o .3 minus is going to become, well, so rather than write h2c .o .3, that would be a correct answer, but just to make it, i guess, a little easier to see, you could write h303h.
01:59
And so that's actually, it's going to look like a central carbon.
02:14
So here you go.
02:15
Here's the starting material with three loan pairs and negative charge on one of these oxygens...