1. When adding a reagent as indicated for each equilibrium shown below, predict whether it will shift to
the left, right, or unchanged.
Equilibrium Reagent Added Shifting Direction
CaF?(s) ? CaΒ²? + 2F? CaCl?
CaF?(s) ? CaΒ²? + 2F? KF
HCN ? H? + CN? KCN
HCN ? H? + CN? HCl
HCN ? H? + CN? KCl
2. Predict the shifting direction of the equilibrium 2SO?(g) ? 2SO?(g) + O?(g) under each of the
following added condition changes, where the standard enthalpy change is ?HΒ° = 197.78 kJ/mol.
a. Increasing the temperature.
b. Increasing the pressure.
c. Adding O? when the reaction is at equilibrium.
d. Removing O? from the system at equilibrium.