Which of the following reagents and conditions would best serve to convert but-1-yne to 1,1dibromobutane?
2 equivalents of HBr , no peroxides
2 equivalents of HBr , with peroxides
1 equivalent of \( \mathrm{Br}_{2} \)
2 equivalents of \( \mathrm{Br}_{2} \) followed by i equivalen