A. Write solubility product (Ksp) expression.
1. CaPO2.
2. BaCHO4.
3. AlCO3.
4. AgCN.
5. HgCl.
B. Calculate Ksp given solubility.
1. The molar solubility of manganese(II) hydroxide, Mn(OH)2, is 2.26 x 10^-10 at 25°C. Calculate the solubility product constant, Ksp, for manganese(II) hydroxide.
C. Calculate solubility given Ksp.
1. What is the molar solubility of AgI at 25°C? The solubility product constant for silver iodide is 8.3 x 10^-17.
2. What is the solubility in g/L of iron(III) hydroxide at 25°C? The solubility product constant for iron(III) hydroxide is 2.5 x 10^-10.
D. Predicting solubility.
1. Which of the following salts has the lowest molar solubility?
a. SrCO3, Ksp = 9.3 x 10^10.
b. MnS, Ksp = 2.5 x 10^-1.
c. BaCrO4, Ksp = 1.2 x 10^-100.
d. BaSO4, Ksp = 1.1 x 10^-10.
2. Which of the following compounds has the lowest solubility in mol/L in water?
a. Al(OH)3, Ksp = 2.1 x 10^-32.
b. CdS, Ksp = 1.0 x 10^-1.
c. PbSO4, Ksp = 1.3 x 10^-1.
d. Sn(OH)2, Ksp = 3.1 x 10^-27.
e. MgCO3, Ksp = 8.6 x 10^-5.
E. Solubility: Common Ion.
1. What is the molar solubility of MgF2 in a 0.56 M Mg(NO3)2 solution? For MgF2, Ksp = 8.4 x 10^-2.
2. What is the molar solubility of iron(III) hydroxide in a buffer solution of pH 11.5? For Fe(OH)3, Ksp = 4.8 x 10^-20.