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Chemical reactions and Stoichiometry

In chemistry, a chemical reaction is a process that leads to the transformation of one set of chemical substances to another set of chemical substances. In order of increasing rate, the most common types of reactions are oxidation, reduction, and hydrolysis; collectively they are known as redox reactions. The substance involved in a chemical reaction is called a reactant. In a chemical reaction, reactants are transformed into products through a series of well-defined steps. These steps are typically accompanied by a change in the chemical equilibrium of the reaction system, but may also be modified by heat (thermal reactions), light (photochemical reactions) or the presence of catalysts. In a chemical reaction, the reactant molecules often break up into several different products, but the chemical bonds between the reactant molecules are usually broken in only one step, in a process called a decomposition reaction. The products of a chemical reaction are usually not the same as the reactants. For example, in the combustion of wood, carbon dioxide and water are formed, but the original wood polymers are broken up into many different products, such as carbon, hydrogen, oxygen, and nitrogen. The breaking of chemical bonds is a fundamental aspect of all chemical reactions. Many chemical processes involve the use of chemical reagents and chemical catalysts. In general, chemical reagents are the species entering the reaction. Chemical catalysts are not consumed by the reaction, but may be converted to the product. In an industrial chemical process, catalysts are often subject to extremely harsh conditions, such as high temperatures, pressures, or chemical compounds that are highly reactive.

Chemical Equations

585 Practice Problems
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03:06
Shriver & Atkins’ Inorganic Chemistry

Using hard-soft concepts, which of the following reactions are predicated to have an equilibrium constant greater than 1 ? Unless otherwise stated, assume gas-phase or hydrocarbon solution and $25^{\circ} \mathrm{C}$
(a) $\mathrm{R}_{3} \mathrm{PBBr}_{3}+\mathrm{R}_{3} \mathrm{NBF}_{3} \rightleftharpoons \mathrm{R}_{3} \mathrm{PRBF}_{3}+\mathrm{R}_{3} \mathrm{NBBr}_{3}$
(b) $\mathrm{SO}_{2}+\left(\mathrm{C}_{6} \mathrm{H}_{5}\right)_{3} \mathrm{P}: \mathrm{HOC}\left(\mathrm{CH}_{3}\right)_{3} \rightleftharpoons\left(\mathrm{C}_{6} \mathrm{H}_{5}\right)_{3} \mathrm{PSO}_{2}+\mathrm{HOC}\left(\mathrm{CH}_{3}\right)_{3}$
(c) $\mathrm{CH}_{3} \mathrm{HgI}+\mathrm{HCl} \rightleftharpoons \mathrm{CH}_{3} \mathrm{HgCl}+\mathrm{HI}$
(d) $\left[\mathrm{AgCl}_{2}\right]^{2-(\mathrm{aq})}+2 \mathrm{CN}^{-}(\mathrm{aq}) \rightleftharpoons\left[\mathrm{Ag}(\mathrm{CN})_{2}\right]^{-(a q)}+2 \mathrm{Cl}^{-(a q)}$

Acids and bases
Prashant Bana
02:21
Chemistry: Introducing Inorganic, Organic and Physical Chemistry

The mechanism for the formation of a DNA double helix from two strands $A \text { and } B \text { is as follows. (Section } 9.6)$
(a) Experiments show that the overall reaction is first order with respect to strand A and first order with respect to strand B. Write the equation for the overall reaction.
(b) Write the rate equation for the overall reaction.
(c) Assuming the processes involved are elementary reactions, derive an expression for the rate constant for the overall reaction in terms of the rate constants for the individual steps.

Reaction kinetics
Lottie Adams
01:21
Chemistry: Introducing Inorganic, Organic and Physical Chemistry

Rate constants at a series of temperatures were obtained for the decomposition of azomethane
\[
\mathrm{CH}_{3} \mathrm{N}_{2} \mathrm{CH}_{3} \rightarrow 2 \mathrm{CH}_{3}^{*}+\mathrm{N}_{2}
\]
$$\begin{array}{llllll}
\hline T / \mathrm{K} & 523 & 541 & 560 & 576 & 593 \\
k / 10^{-6} \mathrm{s}^{-1} & 1.8 & 15 & 60 & 160 & 950
\end{array}$$
Use the data in the table to find the activation energy, $E_{a}$, for the reaction. (Section $9.7)$

Reaction kinetics
Lottie Adams

Classifying Chemical Reactions

158 Practice Problems
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03:54
Chemistry: Introducing Inorganic, Organic and Physical Chemistry

Identify the products and write balanced equations for the following reactions (Section 26.2):
(a) adding caesium to water;
(b) burning rubidium in an excess of air;
(c) heating lithium nitrate.

s-Block chemistry
Pronoy Sinha
04:22
Chemistry: Introducing Inorganic, Organic and Physical Chemistry

Predict the products and write balanced equations for the following reactions (Section 25.2):
(a) $\quad \mathrm{CsH}+$ water
(b) $\quad B_{2} H_{6}+$ pyridine
(c) $\quad \mathrm{S}_{2} \mathrm{H}_{6}+$ oxygen
(d) $\quad \mathrm{N}_{2} \mathrm{H}_{4}+\mathrm{HNO}_{3}(\mathrm{aq})$

Hydrogen
Pronoy Sinha
07:20
Chemistry: Introducing Inorganic, Organic and Physical Chemistry

Suggest structures for the major products formed in the following reactions and state whether these are formed by $\mathrm{S}_{\mathrm{N}} 1, \mathrm{S}_{\mathrm{N}} 2, \mathrm{E} 1,$ or $\mathrm{E} 2$ mechanisms. Explain your reasoning.

Halogenoalkanes: substitution and elimination reactions
Nicholas Sacco

Reaction Stoichiometry

197 Practice Problems
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03:21
Chemistry: Introducing Inorganic, Organic and Physical Chemistry

Write the rate equation for the following elementary reactions and give the molecularity for each reaction. (Sections 9.4 and 9.8)
(a) $\mathrm{Cr}+\mathrm{O}_{3} \rightarrow \mathrm{ClO}^{*}+\mathrm{O}_{2}$
(b) $\mathrm{CH}_{3} \mathrm{N}_{2} \mathrm{CH}_{3} \rightarrow 2 \mathrm{CH}_{3}^{*}+\mathrm{N}_{2}$
(c) $2 \mathrm{Cl}^{\prime} \rightarrow \mathrm{Cl}_{2}$
(d) $\mathrm{NO}_{2}^{*}+\mathrm{F}_{2} \rightarrow \mathrm{NO}_{2} \mathrm{F}+\mathrm{F}$

Reaction kinetics
Lottie Adams
07:45
Physical Chemistry

Nitrogen trioxide dissociates according to the reaction
$$\mathrm{N}_{2} \mathrm{O}_{3}(\mathrm{g})=\mathrm{NO}_{2}(\mathrm{g})+\mathrm{NO}(\mathrm{g})$$
When onc mole of $\mathrm{N}_{2} \mathrm{O}_{3}(\mathrm{g})$ is held at $25^{\circ} \mathrm{C}$ and 1 bar total pressure until equilibrium is reached, the extent of reaction is 0.30 What is $\Delta_{\mathrm{r}} G^{\circ}$ for this reaction at $25^{\circ} \mathrm{C} ?$
$$2 \mathrm{HI}(\mathrm{g})=\mathrm{H}_{2}(\mathrm{g})+\mathrm{I}_{2}(\mathrm{g})$$
at $698.6 \mathrm{K}, K=1.83 \times 10^{-2}$. (a) How many grams of hydrogen iodide will be formed when $10 \mathrm{g}$ of iodine and $0.2 \mathrm{g}$ of hydrogen are heated to this temperature in a 3 -L vessel? ( $b$ ) What will be the partial pressures of $\mathrm{H}_{2}, \mathrm{I}_{2},$ and $\mathrm{HI} ?$
at $698.6 \mathrm{K}, K=1.83 \times 10^{-2}$. (a) How many grams of hydrogen iodide will be formed when $10 \mathrm{g}$ of iodine and $0.2 \mathrm{g}$ of hydrogen are heated to this temperature in a 3 -L vessel? ( $b$ ) What will be the partial pressures of $\mathrm{H}_{2}, \mathrm{I}_{2},$ and $\mathrm{HI} ?$

Chemical Equilibrium
Shubham Kumar
08:27
Atkins' Physical Chemistry

The equilibrium constant for the reaction, $\mathrm{I}_{2}(\mathrm{s})+\mathrm{Br}_{2}(\mathrm{g}) \rightleftharpoons 2 \mathrm{IBr}(\mathrm{g})$ is 0.164 at $25^{\circ} \mathrm{C}$. (a) Calculate $\Delta_{r} G^{\ominus}$ for this reaction. (b) Bromine gas is introduced into a container with excess solid iodine. The pressure and temperature are held at 0.164 atm and $25^{\circ} \mathrm{C}$, respectively. Find the partial pressure of IBr(g) at equilibrium. Assume that all the bromine is in the gaseous form and that the vapour pressure of iodine is negligible. (c) In fact, solid iodine has a measurable vapour pressure at $25^{\circ} \mathrm{C}$. In this case, how would the calculation have to be modified?

Chemical equilibrium
The equilibrium constant
Ayushi Sambyal

Limiting Reactant

68 Practice Problems
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01:13
Introduction to General, Organic and Biochemistry

Consider the equilibrium reaction shown in Problem $7.62 .$ Suppose an equilibrium mixture contains $0.036 M \mathrm{N}_{2}$ and $0.15 \mathrm{M} \mathrm{H}_{2} .$ The equilibrium constant, $K,$ is equal to 0.29 at a certain temperature. What is the concentration of $\mathrm{NH}_{3} ?$

Reaction Rates and Chemical Equilibrium
Evey Z
02:11
Introduction to General, Organic and Biochemistry

Lead(II) nitrate and aluminum chloride react according to the following equation: $3 \mathrm{Pb}\left(\mathrm{NO}_{3}\right)_{2}+2 \mathrm{AlCl}_{3} \longrightarrow 3 \mathrm{PbCl}_{2}+2 \mathrm{Al}\left(\mathrm{NO}_{3}\right)$ In an experiment, 8.00 g of lead nitrate reacted with $2.67 \mathrm{g}$ of aluminum chloride to give $5.55 \mathrm{g}$ of lead chloride.
(a) Which reactant was the limiting reagent?
(b) What was the percent yield?

Chemical Reactions
David Collins
03:02
Chemistry

Limestone (CaCO $_{3}$ ) is decomposed by heating to quicklime (CaO) and carbon dioxide. Calculate how many grams of quicklime can be produced from $1.0 \mathrm{kg}$ of limestone.

Stoichiometry: Ratios of Combination
Daniel Kim

Reaction Yields

87 Practice Problems
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01:07
Introduction to General, Organic and Biochemistry

You want to measure reaction rates for some very fast reactions. What sort of technical difficulties do you expect to arise?

Reaction Rates and Chemical Equilibrium
Evey Z
01:09
Introduction to General, Organic and Biochemistry

(Chemical Connections 7 C) A painkiller -for example, Tylenol-can be purchased in two forms, each containing the same amount of drug. One form is a solid coated pill, and the other is a capsule that contains tiny beads and has the same coat. Which medication will act faster? Explain.

Reaction Rates and Chemical Equilibrium
Evey Z
06:26
Introduction to General, Organic and Biochemistry

Benzene reacts with bromine to produce bromobenzene according to the following equation: $\mathrm{C}_{6} \mathrm{H}_{6}(\ell)+\mathrm{Br}_{2}(\ell) \longrightarrow \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{Br}(\ell)+\mathrm{HBr}(\mathrm{g})$ If $60.0 \mathrm{g}$ of benzene is mixed with $135 \mathrm{g}$ of bromine,
(a) Which is the limiting reagent?
(b) How many grams of bromobenzene are formed in the reaction?

Chemical Reactions and Energy Calculations
Carlene Jimenez

Quantitative Chemical Analysis

108 Practice Problems
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00:56
Chemistry

Predict the outcome of the reactions represented by the following equations by using the activity series, and balance the equations.
(a) $\mathrm{Cu}(s)+\mathrm{HCl}(a q) \longrightarrow$
(b) $\operatorname{Au}(s)+\operatorname{NaBr}(a q) \longrightarrow$
(c) $\operatorname{Mg}(s)+\operatorname{CuSO}_{4}(a q) \longrightarrow$
(d) $\mathrm{Zn}(s)+\mathrm{KBr}(a q) \longrightarrow$

Reactions in Aqueous Solutions
Himanshu Garg
02:43
Organic Chemistry

Suggest a name for alcohol dehydrogenase that would refer to the forward reaction - that is, that would refer to the conversion of acetaldehyde to ethanol.

The Organic Chemistry of the Metabolic Pathways
Prashant Bana
00:51
Chemistry

A quantitative definition of solubility is the maximum number of grams of a solute that will dissolve in a given volume of water at a particular temperature. Describe an experiment that would enable you to determine the solubility of a soluble compound.

Reactions in Aqueous Solutions
Kim Trang Nguyen

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