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Periodic Table properties

In chemistry, a periodic table is a tabular array of the chemical elements arranged by increasing atomic number, electron configuration, and recurring chemical properties. This arrangement shows periodic trends. The rows of the table represent groups, periods, and families of the periodic table. In this way, the table is similar to a family tree—a horizontal representation of groups of related elements. The periodic table is laid out in a grid with horizontal rows called periods and vertical columns called groups. It is a tradition to start a new group with the period's first element, which is called the element's atomic number and the first row's first element. The rows of the table are then enumerated with letters of the local standard alphabet, and the columns are numbered according to the order of the periodic table's elements within each row. The first group is one through the ninth, or groups 1 to 8, except in groups 4, 5, 6, and 7, which are numbered groups 1, 2, 3, and 7 respectively in the IUPAC version of the periodic table. In the periodic table, each horizontal row (group) and each vertical column (period) is numbered with a letter or symbol. The main section of the table is often called the "main table" or "first table" to emphasize that the elements on the main part of the table are more numerous than in other parts of the table. Periodic trends are chemical trends that are common to all elements and are believed to be largely responsible for the periodic table's organization. Each horizontal row is called a family and each vertical column is called a group. The first horizontal row (family) is one through the eighth, or families 1 to 8, except in group 3, which is called group 1. The second through fourth families are called groups 1, 2, 3, and 7 respectively in the International Union of Pure and Applied Chemistry (IUPAC) version of the periodic table. The main trends are listed below. The properties of the elements in a row or column, such as whether an element is a metal or a nonmetal and whether it is an alkali earth or alkali metal, are determined by the electron configurations, atomic radii, ionic radii, and electronegativities of the elements in that row or column. The elements are ordered by increasing atomic number, electronegativity, and ionic radius.

Development of the Periodic table

101 Practice Problems
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02:03
Inorganic Chemistry

Account for the trend in $\mathrm{P}-\mathrm{F}_{\text {axial }}$ distances in the compounds $\mathrm{PF}_{4}\left(\mathrm{CH}_{3}\right), \mathrm{PF}_{3}\left(\mathrm{CH}_{3}\right)_{2},$ and $\mathrm{PF}_{2}\left(\mathrm{CH}_{3}\right)_{3}$. (See
Figure $3.19 .$

Simple Bonding Theory
01:31
Inorganic Chemistry

Elemental Se and Te react with 4-tetrafluoropyridyl silver(I) to afford $\operatorname{Se}\left(\mathrm{C}_{5} \mathrm{F}_{4} \mathrm{N}\right)_{2}$ and $\mathrm{Te}\left(\mathrm{C}_{5} \mathrm{F}_{4} \mathrm{N}\right)_{2}$. Two independent bent molecules were found for each compound in the solid state with $\mathrm{C}-\mathrm{Se}-\mathrm{C}$ angles of $95.47(12)^{\circ}$ and $96.16(13)^{\circ}$ and $\mathrm{C}-\mathrm{Te}-\mathrm{C}$ angles of $90.86(18)^{\circ}$ and $91.73(18)^{\circ}$ respectively (Aboulkacem, S.; Naumann, D.; Tyrra, W.; Pantenburg, I. Organometallics, 2012,31,1559 ).
a. Explain why the angles are more acute for the Te compound relative to the Se compound.
b. These angles are approximately $0.8^{\circ}$ (Se) and $2.0^{\circ}$ (Te) more acute than those in the related pentafluorophenyl $\left(\mathrm{C}_{6} \mathrm{F}_{5}\right)$ compounds. The greater compression of these angles in the 4 -tetrafluoropyridyl compounds has been postulated on the basis of group electronegativity differences. Explain the logic associated with this hypothesis.

Simple Bonding Theory
01:57
Chemistry: Introducing Inorganic, Organic and Physical Chemistry

Predict which compound in each of the following pairs has the higher decomposition temperature: (a) $\mathrm{NaNO}_{3}$ and $\mathrm{KNO}_{3}$ (b) $\mathrm{LiH}$ and $\mathrm{KH} ;(\mathrm{c}) \mathrm{Li}_{2} \mathrm{CO}_{3}$ and $\mathrm{SrCO}_{3}$. Give reasons for your answer. (Section 26.2).

s-Block chemistry
Crystal Wang

Effective Nuclear Charge

24 Practice Problems
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00:45
Chemistry

Explain the term "polarizability." What kind of molecules tend to have high polarizabilities? What is the relationship between polarizability and intermolecular forces?

Intermolecular Forces and Liquids and Solids
Jake Rempel
02:49
Chemistry The Science in Context

Effective nuclear charge $\left(Z_{\text {eff }}\right)$ is related to atomic number
(Z) by a parameter called the shielding parameter $(\sigma)$ according to the equation $Z_{\mathrm{eff}}=Z-\sigma$
a. Calculate $Z_{\mathrm{eff}}$ for the outermost s electrons of Ne and $\mathrm{Ar}$ given $\sigma=4.24$ (for $\mathrm{Ne}$ ) and 11.24 (for $\mathrm{Ar}$ ).
b. Explain why the shielding parameter is much greater for Ar than for Ne.

A Quantum Model of Atoms: Waves, Particles, and Periodic Properties
Madi Sousa
01:38
Physics

A meson with charge - $e$ composed of up and/or down quarks and/or antiquarks.

Particle Physics
Ren Jie Tuieng

Atomic and Ionic sizes

88 Practice Problems
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0:00
Inorganic Chemistry

LiBr has a density of $3.464 \mathrm{g} / \mathrm{cm}^{3}$ and the NaCl crystal structure. Calculate the interionic distance, and compare your answer with the value from the sum of the ionic radii found in Appendix B-1.

The Crystalline Solid State
03:34
Chemistry

The atomic radius of $\mathrm{K}$ is $227 \mathrm{pm}$ and that of $\mathrm{K}^{+}$ is $138 \mathrm{pm}$. Calculate the percent decrease in volume that occurs when $\mathrm{K}(g)$ is converted to $\mathrm{K}^{+}(g)$. (The volume of a sphere is $\frac{1}{3} \pi r^{3}$, where $r$ is the radius of the sphere.)

Electronic Configuration and the Periodic Table
Lottie Adams
06:35
Chemistry

Explain why, for isoelectronic ions, the anions are larger than the cations.

Electronic Configuration and the Periodic Table
Sharfa Farzandh

Ionization Energy

131 Practice Problems
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01:01
Chemistry: An Atoms-Focused Approach

Ionization energies generally increase with increasing atomic number across the second row of the periodic table, but electron affinities generally decrease. Explain the opposing trends.

Atomic Structure: Explaining the Properties of Elements
Megan Lucas
04:22
Inorganic Chemistry

On the basis of electron configurations, explain why
a. sulfur has a lower electron affinity than chlorine.
b. iodine has a lower electron affinity than bromine.
c. boron has a lower ionization energy than beryllium.
d. sulfur has a lower ionization energy than phosphorus.

Atomic Structure
Lijeesh Krishnan
02:19
Chemistry: Introducing Inorganic, Organic and Physical Chemistry

Place the following elements in order of increasing first ionization energy (Section 27.1):
(a) antimony, arsenic, bismuth, nitrogen, phosphorus;
(b) carbon, fluorine, nitrogen, oxygen.

p-Block chemistry
Nicole Smina

Electron Affinity

46 Practice Problems
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01:27
Inorganic Chemistry

The proton affinities of acetone, diethylketone, and benzophenone are $812.0,836.0,$ and $882.3 \mathrm{kJ} / \mathrm{mol}$, respectively. Rationalize the ranking of these values. (Data from C. Laurence and J.-F. Gal, Lewis Basicity and Affinity Scales Data and Measurement, John Wiley and Sons, United Kingdom, $2010,$ p. $5 . .$)

Acid–Base and Donor–Acceptor Chemistry
02:26
Chemistry

Explain the trends in electron affinity from aluminum to chlorine (see Figure 7.10 ).

Electronic Configuration and the Periodic Table
Lottie Adams
01:09
General Chemistry: Principles and Modern Applications

The following properties of astatine have been measured or estimated: (a) covalent radius; (b) ionic radius $\left(\mathrm{At}^{-}\right) ;$ (c) first ionization energy; (d) electron affinity; (e) electronegativity; (f) standard reduction potential. Based on periodic relationships and data in Table $22.4,$ what values would you expect for these properties?

Chemistry of the Main-Group Elements II: Groups 18, 17, 16, 15, and Hydrogen
Lottie Adams

Metals, Nonmetals, and Metalloids

90 Practice Problems
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02:06
Inorganic Chemistry

Using the angular overlap model, determine the energies of the $d$ orbitals of the metal for each of the following geometries, first for ligands that act as $\sigma$ donors only and second for ligands that act as both $\sigma$ donors and $\pi$ acceptors. Angular overlap energy-level diagrams are required for each possibility.
a. linear ML $_{2}$
b. trigonal-planar ML
c. square-pyramidal ML
d. trigonal-bipyramidal ML $_{5}$ Activate $W$
e. cubic ML $_{8}$ (Hint: A cube is two superimposed settings tetrahedra.)

Coordination Chemistry II: Bonding
Banhishikha Sinha
03:18
Shriver & Atkins’ Inorganic Chemistry

Explain why Group 1 hydroxides are much more corrosive to metals than Group 2 hydroxides.

The Group 2 elements
Dr.  Satish  Ingale
04:26
Chemistry: Introducing Inorganic, Organic and Physical Chemistry

Classify the following hydrides as ionic, covalent, or metallic:
(a) $\mathrm{BeH}_{2} ;(\mathrm{b}) \mathrm{PH}_{3} ;(\mathrm{c}) \mathrm{KH} ;(\mathrm{d}) \mathrm{HCl} ;(\mathrm{e}) \mathrm{FeTiH}_{1.8} .$ For the covalent
hydrides, state whether they exist as discrete molecules or are linked by bridging hydrogen atoms. (Section 25.2 )

Hydrogen
Pronoy Sinha

Trends based on Groups

87 Practice Problems
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06:11
Inorganic Chemistry

Complexes with Zintl ions as ligands possess intriguing structures. An early study reported that reaction of $\mathrm{K}_{3} \mathrm{E}_{7}(\mathrm{E}=\mathrm{P}, \mathrm{As}, \mathrm{Sb})$ with sources of $\mathrm{M}(\mathrm{CO})_{3}(\mathrm{M}=\mathrm{Cr}$ Mo, $\mathrm{W}$ ), in the presence of cryptand $[2.2 .2]$ results in $[\mathrm{K}(2.2 .2)]_{3}\left[\mathrm{M}(\mathrm{CO})_{3}\left(\mathrm{E}_{7}\right)\right](\mathrm{S} . \text { Charles, } \mathrm{B} . \mathrm{W} . \text { Eichhorn, } \mathrm{A}$ L. Rheingold, S. G. Bott, $J$. Am. Chem. Soc., 1994, 116 8077 ). Why do these reactions require cryptand[2.2.2] to be successful? Discuss the relative $\pi$ -donor abilities of these Zintl ions to the $\mathrm{Cr}(\mathrm{CO})_{3}$ fragment (Hint: use $\operatorname{IR} \nu(\mathrm{CO}) \text { data }) .$ What trend is observed in the electronic spectra for the $[\mathrm{K}(2.2 .2)]_{3}\left[\mathrm{Cr}(\mathrm{CO})_{3}\left(\mathrm{E}_{7}\right)\right]$ series? Briefly explain why this trend seems reasonable on the basis of how it is assigned. These trianions can be protonated to afford dianions. Sketch $\left[\mathrm{Cr}(\mathrm{CO})_{3}\left(\mathrm{HSb}_{7}\right)\right]^{2-}$ to clearly indicate the protonated site.

Parallels between Main Group and Organometallic Chemistry
04:53
Introduction to General, Organic and Biochemistry

The elements game, Part I. Name and give the sym-
bol of the element that is named for each person.
(a) Niels Bohr $(1885-1962),$ Nobel Prize for physics in 1922
(b) Pierre and Marie Curie, Nobel Prize for chemistry in 1903(c) Albert Einstein $(1879-1955),$ Nobel Prize for physics in 1921
(d) Enrico Fermi $(1901-1954),$ Nobel Prize for physics in 1938
(e) Ernest Lawrence $(1901-1958),$ Nobel Prize for physics in 1939
(f) Lise Meitner $(1868-1968),$ codiscoverer of nuclear fission
(g) Dmitri Mendeleyev $(1834-1907),$ first person to formulate a workable Periodic Table
(h) Alfred Nobel $(1833-1896),$ discoverer of dynamite
(i) Ernest Rutherford $(1871-1937),$ Nobel Prize for chemistry in 1908
(j) Glen Seaborg $(1912-1999),$ Nobel Prize for chemistry in 1951

Atoms
David Collins
00:57
Chemistry

Group the following elements in pairs that you would expect to show similar chemical properties: I, Ba, O, Br, S, and Ca.

Atoms, Molecules, and Ions

Formal Charges

5 Practice Problems
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0:00
Inorganic Chemistry

Formal bond orders can sometimes be misleading. For example, $\left[\mathrm{Re}_{2} \mathrm{Cl}_{9}\right]^{-},$ which has a metal-metal bond order of $3.0,$ has a longer $\mathrm{Re}-$ Re bond $(270.4 \mathrm{pm})$ than $\left[\mathrm{Re}_{2} \mathrm{Cl}_{0}\right]^{2-},(247.3 \mathrm{pm}),$ which has a bond order of 2.5 Account for the shorter bond in $\left[\mathrm{Re}_{2} \mathrm{Cl}_{9}\right]^{2-}$ (Hint: see G. A. Heath, J. E. McGrady, R. G. Raptis, A. C. Willis, Inorg. Chem. , 1996 , 35 , 6838.)

Parallels between Main Group and Organometallic Chemistry
00:49
Chemistry The Science in Context

Explain why so many transition metals form ions with a $2+$ charge.

A Quantum Model of Atoms: Waves, Particles, and Periodic Properties
Sam Limsuwannarot
01:36
Chemistry

For the molecules in Table 19.6 (page 779) that must be described as resonance hybrids, draw electron-dot resonance structures, assign formal charges, and indicate which resonance structure(s) is (are) most important. In addition, indicate which of the molecules in Table 19.6 are paramagnetic.

The Main-Group Elements
Grigoriy Sereda

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