1. Below is a molecular orbital diagram of the π-orbitals in benzene.
Energy
How many π-electrons does benzene have?
Answer:
In a molecular orbital, the relative energy of the orbitals can be qualitatively determined by ranking them by
the number of bonding interactions they have. A bonding interaction can be represented as constructive
overlap of two adjacent orbitals and an anti-bonding interaction is represented by destructive overlap:
bond
anti-bond
88
88
Rank the following depictions of π molecular orbitals of benzene in order of most to least bonding by filling
the boxes in with the letter corresponding to each orbital.
A
B
C
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bonding