Question

4. For the "C" molecule the following millimeter wave pure rotationat transitions has heen ofserwed (in \( \mathrm{MHz} \) ): \begin{tabular}{|c|c|c|c|} \hline Thananthen & \( v=0 \) & \( y-1 \) & \( y=-2 \) \\ \hline\( y=-0 \) & stakn & \( 48\left(673 m^{m}\right. \) & \( 48,280,887 \) \\ \hline\( x=2-\infty \) & \( 9, a m, 9 \times 0 \) & \( 97.2700 x 3 \) & \( 8,5600,30 \) \\ \hline \( 4-3-2 \) & \( 14 n+3 n \) & 145.84 867 & \( 144,818,826 \) \\ \hline\( L=x \) & 18, & 14433431 & 103,113959 \\ \hline \end{tabular} \[ A-A-B \] (a) For each vbrational level derive set of rotational constants by ftting the data. (b) From the results of (a) derve an expression (by fiting) for the vibrational dependence of \( B \). (c) From \( B_{s} \) calculate \( r_{s} \), from \( D_{e} \) calculate \( r_{e} \)

          4. For the "C" molecule the following millimeter wave pure rotationat transitions has heen ofserwed (in \( \mathrm{MHz} \) ):
\begin{tabular}{|c|c|c|c|}
\hline Thananthen & \( v=0 \) & \( y-1 \) & \( y=-2 \) \\
\hline\( y=-0 \) & stakn & \( 48\left(673 m^{m}\right. \) & \( 48,280,887 \) \\
\hline\( x=2-\infty \) & \( 9, a m, 9 \times 0 \) & \( 97.2700 x 3 \) & \( 8,5600,30 \) \\
\hline \( 4-3-2 \) & \( 14 n+3 n \) & 145.84 867 & \( 144,818,826 \) \\
\hline\( L=x \) & 18, & 14433431 & 103,113959 \\
\hline
\end{tabular}
\[
A-A-B
\]
(a) For each vbrational level derive set of rotational constants by ftting the data.
(b) From the results of (a) derve an expression (by fiting) for the vibrational dependence of \( B \).
(c) From \( B_{s} \) calculate \( r_{s} \), from \( D_{e} \) calculate \( r_{e} \)

4. For the "C" molecule the following millimeter wave pure rotationat transitions has heen ofserwed (in MHz ):

Thananthen v=0 y-1 y=-2

y=-0 stakn 48(673 m^m. 48,280,887

x=2-∞ 9, a m, 9 × 0 97.2700 x 3 8,5600,30

4-3-2 14 n+3 n 145.84 867 144,818,826

L=x 18, 14433431 103,113959

A-A-B

(a) For each vbrational level derive set of rotational constants by ftting the data.
(b) From the results of (a) derve an expression (by fiting) for the vibrational dependence of B.
(c) From Bs calculate rs, from De calculate re

Added by Jessica H.

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