A constant-volume calorimeter was calibrated by carrying out a reaction known to release 2.24 kJ of heat in 0.400 L of solution in the calorimeter (q=-2.24kJ), resulting in a temperature rise of 3.76 C. In a subsequent experiment, 200.0mL of 0.30 M HClO2 (aq) and 200.0 mL of 0.30 M NaOH (aq) were mixed in the same calorimeter and the temperature rose by 6.89 C. What is the change in the internal energy of the reaction mixture as a result of the neutralization reaction?