Assuming equal concentrations of conjugate base and acid, which one of the following mixtures is suitable for making a buffer solution with an optimum pH of 3.2-3.5?
CH3COONa / CH3COOH (Ka = 1.8 x 10^–5)
NH3 / NH4Cl (Ka = 5.6 x 10^–10)
NaOCl / HOCl (Ka = 3.2 x 10^–8)
NaNO2 / HNO2 (Ka = 4.5 x 10^–4)
NaCl / HCl