Question 5
Oxidation of glucose to carbon dioxide and water can occurs by combustion in the laboratory or by biological oxidation in living cells (see figure glucose degradation & synthesis in the slides). When combustion is carried out under controlled conditions, the reaction is highly exothermic, with an enthalpy change of -673 kcal/mol. The delta G for this reaction at 25 °C is -686 kcal/mol, so the reaction is also highly exergonic.
a) (0.25 points) explain what the delta H and delta G values mean. What do the negative signs mean in each case?
b) (0.25 points) without doing any calculations, would you expect delta S for this reaction to be positive or negative? Explain.
c) (0.25 points) Now calculate the delta S for this reaction at 25° C. Does the calculated value agree in sign with your prediction in part b?
d) (0.25 points) what are the values of delta G, delta H and delta S for the reverse reaction (synthesis of glucose)?