00:01
If we look at experiments 1 and 2, you'll see that the concentration of a is staying constant, but the concentration of b is doubled.
00:23
It goes from 0 .15 molar to 0 .30 molar.
00:28
When that happens, the rate is quadrupled.
00:34
It goes from 2 times 10 to negative 5 to 8 times 10 to the negative 5.
00:45
This is representative of second order.
00:52
So if we've got 2 to the 2, that gives us our quadrupling.
00:57
So it's second order in b, which is what was changing.
01:09
Then if we look at experiments, one and three, we have the concentration of b.
01:27
No, that's changing two.
01:31
Okay.
01:32
So let's look at experiments.
01:35
I guess it doesn't matter.
01:37
Sure, one and three.
01:38
There are no two experiments where the concentration of b is constant...