The first excited state for a quantum harmonic oscillator is described by the wave
function $\psi(x) = (\frac{\alpha}{\pi})^{1/4}\sqrt{(2\alpha)}xe^{-\alpha x^2/2}$ where $\alpha = m\omega_0/\hbar$ ($\omega_0$ is defined on your
equation sheet). Plug this function into the time-independent Schrödinger equation
$\frac{-\hbar^2}{2m}\frac{d^2\psi}{dx^2} + \frac{1}{2}kx^2\psi = E\psi$ and take the necessary derivatives to show that you get an
energy of $\frac{3}{2}\hbar\omega_0$.