The last model studied here represents a meso form model that possesses stereogenic centers with chirality. This situation arises when one or more identical equal oppositely substituted stereogenic centers are present.
According to convention, the letter E designates the configuration of a stereogenic center. The four atoms attached to the stereogenic center are arranged in priority order according to atomic number; the higher the atomic number, the higher the priority. If two atoms have the same atomic number, move to the next atoms away from the stereogenic center, even further, until a difference in atomic number is found. When viewing the molecule from the side opposite the group with the lowest priority, the remaining three groups are ordered from highest to lowest priority in a clockwise or counterclockwise configuration.
Construct a node diagram for the following molecule:
CH3-CH(CH3)-CH(CH3)-CH3
32. Which carbon in the chain is the stereogenic center?
33. What are the four groups attached to this stereogenic center?
34. Which group has the highest priority?
35. Which group has the lowest priority?