The ratio of reactivity of tertiary:secondary:primary hydrogen atoms in a bromination reaction at 400 K is 1600:82:1. Using this information, calculate the percentage of 1-bromo-2methylpropane that would be expected in a monochlorination reaction of of 2-methylpropane. 1 \( \qquad \) (
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- 2-methylpropane has 9 hydrogen atoms: 1 tertiary and 8 primary. Show more…
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For the chlorination of propane, the two isomers shown here are possible. Propane has six hydrogen atoms on terminal carbon atoms-called primary $\left(1^{\circ}\right)$ hydrogen atoms-and two hydrogen atoms on the interior carbon atom-called secondary $\left(2^{\circ}\right)$ hydrogen atoms. a. If the two different types of hydrogen atoms were equally reactive, what ratio of 1-chloropropane to 2-chloropropane would we expect as monochlorination products? b. The result of a reaction yields 55$\% 2$-chloropropane and 45$\%$ 1-chloropropane. What can we conclude about the relative reactivity of the two different kinds of hydrogen atoms? Determine a ratio of the reactivity of one type of hydrogen atom to the other.
For the chlorination of propane, the two isomers shown here are possible. Propane has six hydrogen atoms on terminal carbon atoms- called primary (1 ) hydrogen atoms-and two hydrogen atoms on the interior carbon atom-called secondary (2 ) hydrogen atoms. a. If the two different types of hydrogen atoms were equally reactive, what ratio of 1-chloropropane to 2-chloropropane would we expect as monochlorination products? b. The result of a reaction yields 55% 2-chloropropane and 45% 1-chloropropane. What can we conclude about the relative reactivity of the two different kinds of hydrogen atoms? Determine a ratio of the reactivity of one type of hydrogen atom to the other.
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