Problem 4.87 Magnetic frustration. Consider three spin-1/2 particles arranged on the corners of a triangle and interacting via the Hamiltonian $H = J(S_1 \cdot S_2 + S_2 \cdot S_3 + S_3 \cdot S_1)$, (4.227) where $J$ is a positive constant. This interaction favors opposite alignment of neigh- boring spins (antiferromagnetism, if they are magnetic dipoles), but the triangular arrangement means that this condition cannot be satisfied simultaneously for all three pairs (Figure 4.18). This is known as geometrical \"frustration.\" (a) Show that the Hamiltonian can be written in terms of the square of the total spin, $S^2$, where $S = \sum_i S_i$. (b) Determine the ground state energy, and its degeneracy. (c) Now consider four spin-1/2 particles arranged on the corners of a square, and interacting with their nearest neighbors: $H = J(S_1 \cdot S_2 + S_2 \cdot S_3 + S_3 \cdot S_4 + S_4 \cdot S_1)$. (4.228) In this case there is a unique ground state. Show that the Hamiltonian in this case can be written $H = \frac{J}{2} \left[ S^2 - (S_1 + S_3)^2 - (S_2 + S_4)^2 \right]$. (4.229) What is the ground state energy?
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Problem 5: 8 points. Two spin-half fermions are in some external potential with single-particle energy levels En and normalized wavefunctions ̄̄n (̄̄0 is the ground state etc.). Their only interaction is through their spins, in the form Hint = ̄̄S₁ · S₂ where S₁,₂ are the spins of the fermions and ̄̄ a real constant. a) The fermions are in the normalized state ̄̄ = ̄̄₀(̄̄₁)̄̄₀(̄̄₂)̄̄ where ̄̄₁,₂ are the coordinates of the fermions and ̄̄ is a state of their spins. Determine ̄̄ by expressing in terms of the basis states |uu⟩, |ud⟩, |du⟩, |dd⟩ where, as usual |uu⟩ is the state with both spins having z-component +ħ/2 etc. b) Find the energy of the state of part (a) (it is an energy eigenstate). c) The fermions are now in the normalized state ̄̄' = (̈̄₀(̄̄₁)̈̄₁(̄̄₂) − ̈̄₀(̄̄₂)̈̄₁(̄̄₁))̄̄' with ̄̄' a new state of their spins which is an eigenstate of the z-component of the total spin Sz = S1z + S2z. Determine the possible states ̄̄' and give the value of Sz for each. d) Find the energy of the states of part (c) and their degeneracy.
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Q.1: Consider a system consisting of 8 particles, each particle with spin direction up or down. (a) What is the total number of states of this system? (b) What is the number of states in which 4 particles have spin up and 4 particles have spin down? Q.2: A system possesses three energy levels 0, ε, and 2ε, in equilibrium with a reservoir at τ = 0.5 eV, with degeneracies g(ε₁)= g(ε₃)=1 and g(ε₂)=3, ε = 1 eV. The particles are distinguishable. a) Find the partition function of the system. b) What is probability that the 2ε level is occupied? c) Find the average energy of a particle. d) What is the average energy of 10 such particles? e) Calculate the Helmholtz free energy. kᐢ = 1.38 ×10⁻²³ J/K= 8.617 × 10⁻⁵ eV/K Q.3: Consider one free particle confined to a cube of side L. Find the concentration nᵥ (in terms of the quantum concentration nဢ) for which the ground state energy is equal to the temperature τ . Q.4: There are xN atoms of type A and (1-x)N atoms of type B on a large lattice with N lattice sites (N >> 1). The atoms are randomly distributed. The entropy can be written on the form: σ = Nf(x). a) Use the formalism of the microcanonical ensemble to find the function f(x). b) Find the value of x for which σ is a maximum.
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