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University Physics with Modern Physics

Hugh D. Young

Chapter 42

Molecules and Condensed Matter - all with Video Answers

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Chapter Questions

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Problem 1

If the energy of the $H_{2}$ covalent bond is -4.48 eV, what wavelength of light is needed to break that molecule apart? In what part of the electromagnetic spectrum does this light lie?

Susan Hallstrom
Susan Hallstrom
Numerade Educator
07:55

Problem 2

An Ionic Bond. (a) Calculate the electric potential energy for a K$^+$ ion and a Br$^-$ ion separated by a distance of 0.29 nm, the equilibrium separation in the KBr molecule. Treat the ions as point charges. (b) The ionization energy of the potassium atom is 4.3 eV. Atomic bromine has an electron affinity of 3.5 eV. Use these data and the results of part (a) to estimate the binding energy of the KBr molecule. Do you expect the actual binding energy to be higher or lower than your estimate? Explain your reasoning.

Kyle Godbey
Kyle Godbey
Numerade Educator
04:29

Problem 3

For the H$_2$ molecule the equilibrium spacing of the two protons is 0.074 nm. The mass of a hydrogen atom is 1.67 $\times$ 10$^-$$^2$$^7$ kg. Calculate the wavelength of the photon emitted in the rotational transition $l$ = 2 to $l$ = 1.

Kai Chen
Kai Chen
Princeton University
03:01

Problem 4

During each of these processes, a photon of light is given up. In each process, what wavelength of light is given up, and in what part of the electromagnetic spectrum is that wavelength? (a) A molecule decreases its vibrational energy by 0.198 eV; (b) an atom decreases its energy by 7.80 eV; (c) a molecule decreases its rotational energy by 4.80 $\times$ 10$^-$$^3$ eV.

Kyle Godbey
Kyle Godbey
Numerade Educator
05:22

Problem 5

A hypothetical NH molecule makes a rotational-level transition from $l$ = 3 to $l$ = 1 and gives off a photon of wavelength 1.780 nm in doing so. What is the separation between the two atoms in this molecule if we model them as point masses? The mass of hydrogen is 1.67 $\times$ 10$^-$$^2$$^7$ kg, and the mass of nitrogen is 2.33 $\times$ 10$^-$$^2$$^6$ kg.

Kai Chen
Kai Chen
Princeton University
04:03

Problem 6

The H$_2$ molecule has a moment of inertia of 4.6 $\times$ 10$^-$$^4$$^8$ kg $\cdot$ m$^2$. What is the wavelength $\lambda$ of the photon absorbed when H$_2$ makes a transition from the $l$ = 3 to the $l$ = 4 rotational level?

Kyle Godbey
Kyle Godbey
Numerade Educator
03:02

Problem 7

The water molecule has an $l$ = 1 rotational level 1.01 $\times$ 10$^-$$^5$ eV above the $l$ = 0 ground level. Calculate the wavelength and frequency of the photon absorbed by water when it undergoes a rotational-level transition from $l$ = 0 to $l$ = 1. The magnetron oscillator in a microwave oven generates microwaves with a frequency of 2450 MHz. Does this make sense, in view of the frequency you calculated in this problem? Explain.

Kai Chen
Kai Chen
Princeton University
02:31

Problem 8

Two atoms of cesium (Cs) can form a Cs $_{2}$ molecule. The equilibrium distance between the nuclei in a $\mathrm{Cs}_{2}$ molecule is $0.447 \mathrm{nm} .$ Calculate the moment of inertia about an axis through the center of mass of the two nuclei and perpendicular to the line joining them. The mass of a cesium atom is $2.21 \times 10^{-25} \mathrm{~kg}$.

Kyle Godbey
Kyle Godbey
Numerade Educator
05:15

Problem 9

The rotational energy levels of CO are calculated in Example 42.2. If the energy of the rotating molecule is described by the classical expression $K$ = \(\frac{1}{2}\) $I$$\omega$$^2$, for the $l$ = 1 level what are (a) the angular speed of the rotating molecule; (b) the linear speed of each atom; (c) the rotational period (the time for one rotation)?

Kai Chen
Kai Chen
Princeton University
05:14

Problem 10

The average kinetic energy of an ideal-gas atom or molecule is \(\frac{3}{2}\) $k$$T$, where $T$ is the Kelvin temperature (Chapter 18). The rotational inertia of the H2 molecule is 4.6 $\times$ 10$^-$$^4$$^8$ kg $\cdot$ m2. What is the value of $T$ for which \(\frac{3}{2}\) $k$$T$ equals the energy separation between the $l$ = 0 and $l$ = 1 energy levels of H$_2$? What does this tell you about the number of H$_2$ molecules in the $l$ = 1 level at room temperature?

Kyle Godbey
Kyle Godbey
Numerade Educator
05:50

Problem 11

A lithium atom has mass 1.17 $\times$ 10$^-$$^2$$^6$ kg, and a hydrogen atom has mass 1.67 $\times$ 10$^-$$^2$$^7$ kg. The equilibrium separation between the two nuclei in the LiH molecule is 0.159 nm. (a) What is the difference in energy between the $l$ = 3 and $l$ = 4 rotational levels? (b) What is the wavelength of the photon emitted in a transition from the $l$ = 4 to the $l$ = 3 level?

Kai Chen
Kai Chen
Princeton University
06:16

Problem 12

If a sodium chloride (NaCl) molecule could undergo an $n$ $\rightarrow$ $n$ $-$ 1 vibrational transition with no change in rotational quantum number, a photon with wavelength 20.0 $\mu$m would be emitted. The mass of a sodium atom is 3.82 $\times$ 10$^-$$^2$$^6$ kg, and the mass of a chlorine atom is 5.81 $\times$ 10$^-$$^2$$^6$ kg. Calculate the force constant $k$$'$ for the interatomic force in NaCl.

Kyle Godbey
Kyle Godbey
Numerade Educator
09:00

Problem 13

When a hypothetical diatomic molecule having atoms 0.8860 nm apart undergoes a rotational transition from the $l$ = 2 state to the next lower state, it gives up a photon having energy 8.841 $\times$ 10$^-$$^4$ eV. When the molecule undergoes a vibrational transition from one energy state to the next lower energy state, it gives up 0.2560 eV. Find the force constant of this molecule.

Brandy Heflin
Brandy Heflin
Numerade Educator
09:01

Problem 14

The vibrational and rotational energies of the CO molecule are given by Eq. (42.9). Calculate the wavelength of the photon absorbed by CO in each of these vibrationrotation transitions: (a) $n$ = 0, $l$ = 2$\rightarrow$ $n$ = 1, $l$ = 3; (b) $n$ = 0, $l$ = 3$\rightarrow$ $n$ = 1, $l$ = 2; (c) $n$ = 0, $l$ = 4$\rightarrow$ $n$ = 1, $l$ = 3.

Kyle Godbey
Kyle Godbey
Numerade Educator
02:51

Problem 15

$\textbf{Density of NaCl}$. The spacing of adjacent atoms in a crystal of sodium chloride is 0.282 nm. The mass of a sodium atom is 3.82 $\times$ 10$^-$$^2$$^6$ kg, and the mass of a chlorine atom is 5.89 $\times$ 10$^-$$^2$$^6$ kg. Calculate the density of sodium chloride.

Kai Chen
Kai Chen
Princeton University
06:00

Problem 16

Potassium bromide (KBr) has a density of 2.75 $\times$ 10$^3$ kg/m$^3$ and the same crystal structure as NaCl. The mass of a potassium atom is 6.49 $\times$ 10$^-$$^2$$^6$ kg, and the mass of a bromine atom is 1.33 $\times$ 10$^-$$^2$$^5$ kg. (a) Calculate the average spacing between adjacent atoms in a KBr crystal. (b) How does the value
calculated in part (a) compare with the spacing in NaCl (see Exercise 42.15)? Is the relationship between the two values qualitatively what you would expect? Explain.

Kyle Godbey
Kyle Godbey
Numerade Educator
03:22

Problem 17

The maximum wavelength of light that a certain silicon photocell can detect is 1.11 $\mu$m. (a) What is the energy gap (in electron volts) between the valence and conduction bands for this photocell? (b) Explain why pure silicon is opaque.

Kai Chen
Kai Chen
Princeton University
05:29

Problem 18

The gap between valence and conduction bands in diamond is 5.47 eV. (a) What is the maximum wavelength of a photon that can excite an electron from the top of the valence band into the conduction band? In what region of the electromagnetic spectrum does this photon lie? (b) Explain why pure diamond is transparent and colorless. (c) Most gem diamonds have a yellow color. Explain how impurities in the diamond can cause this color.

Kyle Godbey
Kyle Godbey
Numerade Educator
03:45

Problem 19

The gap between valence and conduction bands in silicon is 1.12 eV. A nickel nucleus in an excited state emits a gammaray photon with wavelength 9.31 $\times$ 10$^-$$^4$ nm. How many electrons can be excited from the top of the valence band to the bottom of the conduction band by the absorption of this gamma ray?

Zhuxi Luo
Zhuxi Luo
Numerade Educator
04:41

Problem 20

Calculate $v_r$$_m$$_s$ for free electrons with average kinetic energy \(\frac{3}{2}\) $kT$ at a temperature of 300 K. How does your result compare to the speed of an electron with a kinetic energy equal to the Fermi energy of copper, calculated in Example 42.7? Why is there such a difference between these speeds?

Kyle Godbey
Kyle Godbey
Numerade Educator
04:01

Problem 21

Calculate the density of states $g$(E) for the free-electron model of a metal if $E$ $=$ 7.0 eV and $V$ $=$ 1.0 cm$^3$. Express your answer in units of states per electron volt.

Kai Chen
Kai Chen
Princeton University
04:33

Problem 22

The Fermi energy of sodium is 3.23 eV. (a) Find the average energy E$_a$$_v$ of the electrons at absolute zero. (b) What is the speed of an electron that has energy E$_a$$_v$ ? (c) At what Kelvin temperature $T$ is $kT$ equal to $E$$_F$ ? (This is called the $Fermi$ $temperature$ for the metal. It is approximately the temperature at which molecules in a classical ideal gas would have the same kinetic energy as the fastest-moving electron in the metal.)

Kyle Godbey
Kyle Godbey
Numerade Educator
02:35

Problem 23

Silver has a Fermi energy of 5.48 eV. Calculate the electron contribution to the molar heat capacity at constant volume of silver, C$_V$, at 300 K. Express your result (a) as a multiple of $R$ and (b) as a fraction of the actual value for silver, C$_V$ = 25.3 J/mol $\cdot$ K. (c) Is the value of C$_V$ due principally to the electrons? If not, to what is it due? (Hint: See Section 18.4.)

Kai Chen
Kai Chen
Princeton University
03:24

Problem 24

At the Fermi temperature T$_F$, E$_F$ = $k$$T$$_F$ (see Exercise 42.22). When $T$ = $T$$_F$, what is the probability that a state with energy $E$ $=$ $2$$E$$_F$ is occupied?

Kyle Godbey
Kyle Godbey
Numerade Educator
02:23

Problem 25

For a solid metal having a Fermi energy of 8.500 eV, what is the probability, at room temperature, that a state having an energy of 8.520 eV is occupied by an electron?

Nolan Smyth
Nolan Smyth
Numerade Educator
08:43

Problem 26

Pure germanium has a band gap of $0.67 \mathrm{eV}$. The Fermi energy is in the middle of the gap. (a) For temperatures of $250 \mathrm{~K}$, $300 \mathrm{~K},$ and $350 \mathrm{~K},$ calculate the probability $f(E)$ that a state at the bottom of the conduction band is occupied. (b) For each temperature in part (a), calculate the probability that a state at the top of the valence band is empty.

Kyle Godbey
Kyle Godbey
Numerade Educator
05:33

Problem 27

Germanium has a band gap of 0.67 eV. Doping with arsenic adds donor levels in the gap 0.01 eV below the bottom of the conduction band. At a temperature of 300 K, the probability is 4.4 $\times$ 10$^-$$^4$ that an electron state is occupied at the bottom of the conduction band. Where is the Fermi level relative to the conduction band in this case?

Kai Chen
Kai Chen
Princeton University
04:36

Problem 28

(a) Suppose a piece of very pure germanium is to be used as a light detector by observing, through the absorption of photons, the increase in conductivity resulting from generation of electron-hole pairs. If each pair requires 0.67 eV of energy, what is the maximum wavelength that can be detected? In what portion of the spectrum does it lie? (b) What are the answers to part a if the material is silicon, with an energy requirement of 1.12 eV per pair, corresponding to the gap between valence and conduction bands in that element?

Kyle Godbey
Kyle Godbey
Numerade Educator
07:04

Problem 29

At a temperature of 290 K, a certain $p$-$n$ junction has a saturation current $I$$_S$ = 0.500 mA. (a) Find the current at this temperature when the voltage is (i) 1.00 mV, (ii) $-$1.00 mV, (iii) 100 mV, and (iv) $-$100 mV. (b) Is there a region of applied voltage where the diode obeys Ohm's law?

Kai Chen
Kai Chen
Princeton University
05:17

Problem 30

For a certain $p$-$n$ junction diode, the saturation current at room temperature (20$^{\circ}$C) is 0.950 mA. What is the resistance of this diode when the voltage across it is (a) 85.0 mV and (b) $-$50.0 mV ?

Kyle Godbey
Kyle Godbey
Numerade Educator
07:13

Problem 31

(a) A forward-bias voltage of 15.0 mV produces a positive current of 9.25 mA through a $p$-$n$ junction at 300 K. What does the positive current become if the forward-bias voltage is reduced to 10.0 mV? (b) For reverse-bias voltages of $-$15.0 mV and $-$10.0 mV, what is the reverse-bias negative current?

Joshua Young
Joshua Young
Numerade Educator
08:28

Problem 32

A $p$-$n$ junction has a saturation current of 6.40 mA. (a) At a temperature of 300 K, what voltage is needed to produce a positive current of 40.0 mA? (b) For a voltage equal to the negative of the value calculated in part (a), what is the negative current?

Kyle Godbey
Kyle Godbey
Numerade Educator
08:20

Problem 33

A hypothetical diatomic molecule of oxygen $(mass = 2.656 \times 10^{-26} kg)$ and hydrogen $(mass = 1.67 \times 10^{-27} kg)$ emits a photon of wavelength 2.39 $\mu$m when it makes a transition from one vibrational state to the next lower state. If we model this molecule as two point masses at opposite ends of a massless spring, (a) what is the force constant of this spring, and (b) how many vibrations per second is the molecule making?

Kai Chen
Kai Chen
Princeton University
03:41

Problem 34

When a diatomic molecule undergoes a transition from the $l = 2$ to the $l = 1$ rotational state, a photon with wavelength 54.3 $\mu$m is emitted. What is the moment of inertia of the molecule for an axis through its center of mass and perpendicular to the line connecting the nuclei?

Kyle Godbey
Kyle Godbey
Numerade Educator
05:56

Problem 35

(a) The equilibrium separation of the two nuclei in an NaCl molecule is 0.24 nm. If the molecule is modeled as charges $+e$ and $-e$ separated by 0.24 nm, what is the electric dipole moment of the molecule (see Section 21.7)? (b) The measured electric dipole moment of an NaCl molecule is $3.0 \times 10^{-29}$ $C \cdot m$. If this dipole moment arises from point charges $+q$ and $-q$ separated by 0.24 nm, what is $q$? (c) A definition of the $fractional$ $ionic$ $character$ of the bond is $q/e$. If the sodium atom has charge $+e$ and the chlorine atom has charge $-e$, the fractional ionic character would be equal to 1. What is the actual fractional ionic character for the bond in NaCl? (d) Theequilibrium distance between nuclei in the hydrogen iodide (HI) molecule is 0.16 nm, and the measured electric dipole moment of the molecule is $1.5 \times 10^{-30}$ $C \cdot m$. What is the fractional ionic character for the bond in HI? How does your answer compare to that for NaCl calculated in part (c)? Discuss reasons for the difference in these results.

Kai Chen
Kai Chen
Princeton University
07:16

Problem 36

The binding energy of a potassium chloride molecule (KCl) is 4.43 eV. The ionization energy of a potassium atom is 4.3 eV, and the electron affinity of chlorine is 3.6 eV. Use these data to estimate the equilibrium separation between the two atoms in the KCl molecule. Explain why your result is only an estimate and not a precise value.

Kyle Godbey
Kyle Godbey
Numerade Educator
07:44

Problem 37

(a) For the sodium chloride molecule (NaCl) discussed at the beginning of Section 42.1, what is the maximum separation of the ions for stability if they may be regarded as point charges? That is, what is the largest separation for which the energy of an $Na^{+}$ ion and a $Cl^{-}$ ion, calculated in this model, is lower than the energy of the two separate atoms Na and Cl? (b) Calculate this distance for the potassium bromide molecule, described in Exercise 42.2.

Kai Chen
Kai Chen
Princeton University
08:47

Problem 38

When a NaF molecule makes a transition from the $l = 3$ to the $l = 2$ rotational level with no change in vibrational quantum number or electronic state, a photon with wavelength 3.83 mm is emitted. A sodium atom has mass $3.82 \times 10^{-26}$ kg, and a fluorine atom has mass $3.15 \times 10^{-26}$ kg. Calculate the equilibrium separation between the nuclei in a NaF molecule. How does your answer compare with the value for NaCl given in Section 42.1? Is this result reasonable? Explain.

Kyle Godbey
Kyle Godbey
Numerade Educator
14:34

Problem 39

Consider a gas of diatomic molecules (moment of inertia $I$) at an absolute temperature $T$. If $E$$_g$ is a groundstate energy and $E$$_e$$_x$ is the energy of an excited state, then the Maxwell-Boltzmann distribution (see Section 39.4) predicts that the ratio of the numbers of molecules in the two states is $n$$_e$$_x$/$n$$_g$ $=$ $e$$^-$$^($$^E$$^{_e}$$^{_x}$$^-$$^E$$^{_g}$$^)$$^/$$^k$$^T$. (a) Explain why the ratio of the number of molecules in the $l$th rotational energy level to the number of molecules in the ground-state ($l$ $=$ 0) rotational level is \(\frac{nl}{n0}\)$=$ (2$l$ $+$ 1)$e$$^-$$^[$$^l$$^($$^l$$^+$$^1$$^)$$^\hbar$$^{^2}$$^]$$^/$$^2$$^I$$^k$$^T$
(Hint: For each value of $l$, how many states are there with different values of $m$$_l$ ?) (b) Determine the ratio $n$$_l$/$n$$_0$ for a gas of CO molecules at 300 K for (i) $l$ $=$ 1; (ii) $l$ $=$ 2; (iii) $l$ $=$ 10; (iv) $l$ $=$ 20; (v) $l$ $=$ 50. The moment of inertia of the CO molecule is given in Example 42.2 (Section 42.2). (c) Your results in part (b) show that as l is increased, the ratio $n$$_l$/$n$$_0$ first increases and then decreases. Explain why.

Kai Chen
Kai Chen
Princeton University
07:21

Problem 40

Part (a) of Problem 42.39 gives an equation for the number of diatomic molecules in the $l$th rotational level to the number in the ground-state rotational level. (a) Derive an expression for the value of $l$ for which this ratio is the largest. (b) For the CO molecule at $T$ = 300 K, for what value of $l$ is this ratio a maximum? (The moment of inertia of the CO molecule is given in Example 42.2.)

Kyle Godbey
Kyle Godbey
Numerade Educator
10:12

Problem 41

Spectral Lines from Isotopes. The equilibrium separation for NaCl is 0.2361 nm. The mass of a sodium atom is 3.8176 $\times$ 10$^-$$^2$$^6$ kg. Chlorine has two stable isotopes, $^3$$^5$Cl and $^3$$^7$Cl, that have different masses but identical chemical properties. The atomic mass of $^3$$^5$Cl is 5.8068 $\times$ 10$^-$$^2$$^6$ kg, and the atomic mass of $^3$$^7$Cl is 6.1384 $\times$ 10$^-$$^2$$^6$ kg. (a) Calculate the wavelength of the photon emitted in the $l$ $=4 2\rightarrow$ $l$ $=$ 1 and $l$ $=$ 1$\rightarrow$ $l$ $=$ 0 transitions for Na$^3$$^5$Cl. (b) Repeat part (a) for Na$^3$$^7$Cl. What are the differences in the wavelengths for the two isotopes?

Kai Chen
Kai Chen
Princeton University
05:02

Problem 42

Our galaxy contains numerous $molecular$ $clouds$, regions many lightyears in extent in which the density is high enough and the temperature low enough for atoms to form into molecules. Most of the molecules are H$_2$, but a small fraction of the molecules are carbon monoxide (CO). Such a molecular cloud in the constellation Orion is shown in Fig. P42.42. The upper image was made with an ordinary visiblelight telescope; the lower image shows the molecular cloud in Orion as imaged with a radio telescope tuned to a wavelength emitted by CO in a rotational transition. The different colors in the radio image indicate regions of the cloud that are moving either toward us (blue) or away from us (red) relative to the motion of the cloud as a whole, as determined by the Doppler shift of the radiation. (Since a molecular cloud has about 10,000 hydrogen molecules for each CO
molecule, it might seem more reasonable to tune a radio telescope to emissions from H$_2$ than to emissions from CO. Unfortunately, it turns out that the H$_2$ molecules in molecular clouds do not radiate in either the radio or visible portions of the electromagnetic spectrum.) (a) Using the data in Example 42.2 (Section 42.2), calculate the energy and wavelength of the photon emitted by a CO molecule in an $l$ $=$ 1$\rightarrow$ $l$ $=$ 0 rotational transition. (b) As a rule, molecules in a gas at temperature $T$ will be found in a certain excited rotational energy level, provided the energy of that level is no higher than $kT$ (see Problem 42.39). Use this rule to explain why astronomers can detect radiation from CO in molecular clouds even though the typical temperature of a molecular cloud is a very low 20 K.

Kyle Godbey
Kyle Godbey
Numerade Educator
02:11

Problem 43

The force constant for the internuclear force in a hydrogen molecule (H$_2$) is $k$$'$ $=$ 576 N/m. A hydrogen atom has mass 1.67 $\times$ 10$^-$$^2$$^7$ kg. Calculate the zeropoint vibrational energy for H$_2$ (that is, the vibrational energy the molecule has in the $n$ $=$ 0 ground vibrational level). How does this energy compare in magnitude with the H$_2$ bond energy of $-$4.48 eV ?

Kai Chen
Kai Chen
Princeton University
04:24

Problem 44

When an OH molecule undergoes a transition from the $n = 0$ to the $n = 1$ vibrational level, its internal vibrational energy increases by 0.463 eV. Calculate the frequency of vibration and the force constant for the interatomic force. (The mass of an oxygen atom is $2.66 \times 10^{-26}$ kg, and the mass of a hydrogen atom is $1.67 \times 10^{-27} kg.)$

Kyle Godbey
Kyle Godbey
Numerade Educator
09:59

Problem 45

The hydrogen iodide (HI) molecule has equilibrium separation 0.160 nm and vibrational frequency $6.93 \times 10^{13}$ Hz. The mass of a hydrogen atom is $1.67 \times 10^{-27}$ kg, and the mass of an iodine atom is 2.11 $\times$ 10$^-$$^2$$^5$ kg. (a) Calculate the moment of inertia of HI about a perpendicular axis through its center of mass. (b) Calculate the wavelength of the photon emitted in each of the following vibrationrotation transitions: (i) $n = 1$, $l = 1 \rightarrow n = 0$, $l = 0$; (ii) $n = 1$, $l = 2\rightarrow n = 0$, $l = 1$; (iii) $n = 2$, $l = 2\rightarrow n = 1$, $l = 3$.

Kai Chen
Kai Chen
Princeton University
06:18

Problem 46

Suppose the hydrogen atom in HF (see the Bridging Problem for this chapter) is replaced by an atom of deuterium, an isotope of hydrogen with a mass of $3.34 \times 10^{-27}$ kg. The force constant is determined by the electron configuration, so it is the same as for the normal HF molecule. (a) What is the vibrational frequency of this molecule? (b) What wavelength of light corresponds to the energy difference between the $n = 1$ and $n = 0$ levels? In what region of the spectrum does this wavelength lie?

Kyle Godbey
Kyle Godbey
Numerade Educator
04:19

Problem 47

Compute the Fermi energy of potassium by making the simple approximation that each atom contributes one free electron. The density of potassium is $851 kg/m^{3}$, and the mass of a single potassium atom is $6.49 \times 10^{-26}$ kg.

Kai Chen
Kai Chen
Princeton University
12:19

Problem 48

$42.48^{\circ}$ CALC The one-dimensional calculation of Example 42.4 (Section 42.3 ) can be extended to three dimensions. For the threedimensional fce $\mathrm{NaCl}$ lattice, the result for the potential energy of a pair of $\mathrm{Na}^{+}$ and $\mathrm{Cl}^{-}$ ions due to the electrostatic interaction with all of the ions in the crystal is $U=-\alpha e^{2} / 4 \pi \epsilon_{0} r,$ where $\alpha=1.75$ is the Madelung constant. Another contribution to the potential energy is a repulsive interaction at small ionic separation $r$ due to overlap of the electron clouds. This contribution can be represented by $A / r^{8},$ where $A$ is a positive constant, so the expression for the total potential energy is
$$
U_{\mathrm{tot}}=-\frac{\alpha e^{2}}{4 \pi \epsilon_{0} r}+\frac{A}{r^{8}}
$$
(a) Let $r_{0}$ be the value of the ionic separation $r$ for which $U_{\text {tot }}$ is a minimum. Use this definition to find an equation that relates $r_{0}$ and $A,$ and use this to write $U_{\text {tot }}$ in terms of $r_{0}$. For $\mathrm{NaCl}$, $r_{0}=0.281 \mathrm{nm} .$ Obtain a numerical value (in electron volts) of $U_{\text {tot }}$ for $\mathrm{NaCl}$. (b) The quantity $-U_{\text {tot }}$ is the energy required to remove a $\mathrm{Na}^{+}$ ion and a $\mathrm{Cl}^{-}$ ion from the crystal. Forming a pair of neutral atoms from this pair of ions involves the release of $5.14 \mathrm{eV}$ (the ionization energy of Na) and the expenditure of $3.61 \mathrm{eV}$ (the electron affinity of $\mathrm{Cl}$ ). Use the result of part (a) to calculate the energy required to remove a pair of neutral Na and Cl atoms from the crystal. The experimental value for this quantity is $6.39 \mathrm{eV}$ how well does your calculation agree?

Sarah Mccrumb
Sarah Mccrumb
Numerade Educator
04:04

Problem 49

Metallic lithium has a bcc crystal structure. Each unit cell is a cube of side length $a = 0.35 nm$. (a) For a bcc lattice, what is the number of atoms per unit volume? Give your answer in terms of a. (Hint: How many atoms are there per unit cell?) (b) Use the result of part (a) to calculate the zerotemperature Fermi energy $E_{F0}$ for metallic lithium. Assume there is one free electron per atom.

Kai Chen
Kai Chen
Princeton University
16:22

Problem 50

To determine the equilibrium separation of the atoms in the HCl molecule, you measure the rotational spectrum of HCl. You find that the spectrum contains these wavelengths (among others): $60.4 \mu m$, $69.0 \mu m$, $80.4 \mu m$, $96.4 \mu m$, and $120.4 \mu m$. (a) Use your measured wavelengths to find the moment of inertia of the HCl molecule about an axis through the center of mass and perpendicular to the line joining the two nuclei. (b) The value of $l$ changes by $\pm 1$ in rotational transitions. What value of $l$ for the upper level of the transition gives rise to each of these wavelengths? (c) Use your result of part (a) to calculate the equilibrium separation of the atoms in the HCl molecule. The mass of a chlorine atom is $5.81 \times 10^{-26}$ kg, and the mass of a hydrogen atom is $1.67 \times 10^{-27}$ kg. (d) What is the longest-wavelength line in the rotational spectrum of HCl?

Kyle Godbey
Kyle Godbey
Numerade Educator
14:37

Problem 51

The table gives the occupation probabilities $f(E)$ as a function of the energy $E$ for a solid conductor at a fixed temperature $T$. To determine the Fermi energy of the solid material, you are asked to analyze this information in terms of the Fermi-Dirac distribution. (a) Graph the values in the table as $E$ versus ln${[1/f(E)] - 1}$. Find the slope and $y-intercept$ of the best-fit straight line for the data points when they are plotted this way. (b) Use your results of part (a) to calculate the temperature $T$ and the Fermi energy of the material.

Sarah Mccrumb
Sarah Mccrumb
Numerade Educator
10:21

Problem 52

A $p-n$ junction is part of the control mechanism for a wind turbine that is used to generate electricity. The turbine has been malfunctioning, so you are running diagnostics. You can remotely change the bias voltage $V$ applied to the junction and measure the current through the junction. With a forward bias voltage of $+$5.00 mV, the current is $I_f = 0.407 mA$. With a reverse bias voltage of $-5.00 mV$, the current is $I_{r} = -0.338 mA$. Assume that Eq. (42.22) accurately represents the current-voltage relationship for the junction, and use these two results to calculate the temperature $T$ and saturation current $I_{S}$ for the junction. [Hint: In your analysis, let $x= e^{eV/kT}$. Apply Eq. (42.22) to each measurement and obtain a quadratic equation for $x$.]

Kyle Godbey
Kyle Godbey
Numerade Educator
06:21

Problem 53

Consider a system of $N$ free electrons within a volume $V$. Even at absolute zero, such a system exerts a pressure $p$ on its surroundings due to the motion of the electrons. To calculate this pressure, imagine that the volume increases by a small amount $dV$. The electrons will do an amount of work $p$ $dV$ on their surroundings, which means that the total energy $E_{tot}$ of the electrons will change by an amount $dE_{tot} = -p dV$. Hence $p = -dE_{tot}/dV$. (a) Show that the pressure of the electrons at absolute zero is $p = \frac{3^{2/3}\pi^{4/3}\hbar^{2}}{5m} \lgroup \frac{N}{V}\ \rgroup^{5/3}$ (b) Evaluate this pressure for copper, which has a freeelectron concentration of $8.45 \times 10^{28} m^{-3}$. Express your result in pascals and in atmospheres. (c) The pressure you found in part (b) is extremely high. Why, then, don't the electrons in a piece of copper simply explode out of the metal?

Kai Chen
Kai Chen
Princeton University
06:57

Problem 54

When the pressure $p$ on a material increases by an amount $\Delta p$, the volume of the material will change from $V$ to $V + \Delta V$, where $\Delta V$ is negative. The $bulk$ $modulus$ $B$ of the material is defined to be the ratio of the pressure change $\Delta p$ to the absolute value |$\Delta V/V$| of the fractional volume change. The greater the bulk modulus, the greater the pressure increase required for a given fractional volume change, and the more incompressible the material (see Section 11.4). Since $\Delta V$ $< 0$, the bulk modulus can
be written as $B = -\Delta p/(\Delta V/V_{0})$. In the limit that the pressure and volume changes are very small, this becomes $B = -V \frac{dp}{dV}$ (a) Use the result of Problem 42.53 to show that the bulk modulus for a system of $N$ free electrons in a volume $V$ at low temperatures is $B = \frac{5}{3} p$. (Hint: The quantity p in the expression $B = -V(dp/dV)$ is the $external$ $pressure$ on the system. Can you explain why this is equal to the internal pressure of the system itself, as found in Problem 42.53?) (b) Evaluate the bulk modulus for the electrons in copper, which has a freeelectron concentration of $8.45 \times 10^{28} m^{-3}$. Express your result in pascals. (c) The actual bulk modulus of copper is $1.4 \times 10^{11}$ Pa. Based on your result in part (b), what fraction of this is due to the free electrons in copper? (This result shows that the free electrons in a metal play a major role in making the metal resistant to compression.) What do you think is responsible for the remaining fraction of the bulk modulus?

Kyle Godbey
Kyle Godbey
Numerade Educator
08:10

Problem 55

In the discussion of free electrons in Section 42.5, we assumed that we could ignore the effects of relativity. This is not a safe assumption if the Fermi energy is greater than about $\frac{1}{100} mc^2$ (that is, more than about 1% of the rest energy of an electron). (a) Assume that the Fermi energy at absolute zero, as given by Eq. (42.19), is equal to $\frac{1}{100} mc^2$. Show that the electron concentration is $\frac{N}{V} = \frac{2^{3/2}m^3c^3}{3000\pi^2\hslash^3}$
and determine the numerical value of $N/V$. (b) Is it a good approximation to ignore relativistic effects for electrons in a metal such as copper, for which the electron concentration is $8.45 \times 10^{28} m^{-3}$? Explain. (c) A white dwarf star is what is left behind by a star like the sun after it has ceased to produce energy by nuclear reactions. (Our own sun will become a white dwarf star in another 6 \(\times\) 10$^{9}$ years or so.) A typical white dwarf has $mass 2 \times 10^{30} kg$ (comparable to the sun) and radius 6000 km (comparable to that of the earth). The gravitational attraction of different parts of the white dwarf for each other tends to compress the star; what prevents it from compressing is the pressure of free electrons within the star (see Problem 42.53). Use both of the following assumptions to estimate the electron concentration within a typical white dwarf star: (i) the white dwarf star is made of carbon, which has a mass per atom of $1.99 \times 10^{-26} kg$; and (ii) all six of the electrons from each carbon atom are able to move freely throughout the star. (d) Is it a good approximation to ignore relativistic effects in the structure of a white dwarf star? Explain.

Kai Chen
Kai Chen
Princeton University
03:22

Problem 56

The sensitivity of a diode thermometer depends on how much the voltage changes for a given temperature change, with the current remaining constant. What is the sensitivity for this diode thermometer, operated at 100 mA, for a temperature change from 25$^{\circ}$C to 150$^{\circ}$C? (a) $+$0.2 mV/$^{\circ}$C; (b) $+$2.0 mV/$^{\circ}$C;
(c) $-$0.2 mV/$^{\circ}$C; (d) $-$2.0 mV/$^{\circ}$C.

Kyle Godbey
Kyle Godbey
Numerade Educator
04:02

Problem 57

Which statement best explains the temperature dependence of the current-voltage characteristics that the graph shows? At higher temperatures: (a) The band gap is larger, so the electron-hole pairs have more energy, which causes the current at a given voltage to be larger. (b) More electrons can move to the conduction band, which causes the current at a given voltage to be larger. (c) All of the electrons in the valence band move to the conduction band, and the diode behaves like a metal and follows Ohm's law. (d) The acceptor and donor impurity atoms are free to move through the material, which causes the current at a given voltage to be larger.

Kai Chen
Kai Chen
Princeton University
02:28

Problem 58

If the voltage rather than the current is kept constant, what happens as the temperature increases from 25$^{\circ}$C to 150$^{\circ}$C? (a) At first the current increases, then it decreases. (b) The current increases. (c) The current decreases, eventually approaching zero. (d) The current does not change unless the voltage also changes.

Kyle Godbey
Kyle Godbey
Numerade Educator