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Holt Chemistry

R.Thomas Myers, Keith Oldham,Savatore Tocci

Chapter 18

Nuclear Chemistry - all with Video Answers

Educators


Chapter Questions

01:30

Problem 1

What is the energy emitted when a
nucleus forms?

Katherine Mccandless
Katherine Mccandless
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00:37

Problem 2

What is a nucleon?

Matthew Lueckheide
Matthew Lueckheide
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00:43

Problem 3

What is the high-energy electromagnetic
radiation produced by decaying nuclei?

Katherine Mccandless
Katherine Mccandless
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01:22

Problem 4

What nuclear reaction happens when two
small nuclei combine?

Matthew Lueckheide
Matthew Lueckheide
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00:49

Problem 5

Explain the difference between fission
and fusion.

Katherine Mccandless
Katherine Mccandless
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01:39

Problem 6

Name the process that describes an unstable
nucleus that emits particles and energy.

Matthew Lueckheide
Matthew Lueckheide
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01:19

Problem 7

Define critical mass.

Katherine Mccandless
Katherine Mccandless
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01:59

Problem 8

Define half-life.

Matthew Lueckheide
Matthew Lueckheide
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00:32

Problem 9

What is the combination of neutrons and
protons in a nucleus known as?

Katherine Mccandless
Katherine Mccandless
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01:52

Problem 10

Name two types of nuclear changes.

Matthew Lueckheide
Matthew Lueckheide
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01:22

Problem 11

Explain how the strong force holds a
nucleus together despite the repulsive forces
between protons.

Katherine Mccandless
Katherine Mccandless
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00:54

Problem 12

Describe what happens to unstable nuclei.

Matthew Lueckheide
Matthew Lueckheide
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01:15

Problem 13

A. What is the relationship among the number of protons, the number of neutrons, and the stability of the nucleus for small atoms?
B. What is the relationship among number of protons, the number of neutrons, and the stability of the nucleus for large atoms?

Katherine Mccandless
Katherine Mccandless
Numerade Educator
01:21

Problem 14

What is the relationship between binding
energy and the formation of a nucleus from
protons and neutrons?

Matthew Lueckheide
Matthew Lueckheide
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01:21

Problem 15

What is the relationship between mass
defect and binding energy?

Katherine Mccandless
Katherine Mccandless
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02:38

Problem 16

Why is nuclear stability better indicated by
binding energy per nucleon than by total
binding energy per nucleus?

Matthew Lueckheide
Matthew Lueckheide
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00:40

Problem 17

What is a quark?

Katherine Mccandless
Katherine Mccandless
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01:28

Problem 18

What is the relationship between an alpha
particle and a helium nucleus?

Matthew Lueckheide
Matthew Lueckheide
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01:46

Problem 19

Compare the penetrating powers of alpha
particles, beta particles, and gamma rays.

Katherine Mccandless
Katherine Mccandless
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02:02

Problem 20

Is the decay of an unstable isotope into a
stable isotope always a one-step process?
Explain.

Matthew Lueckheide
Matthew Lueckheide
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03:50

Problem 21

a. What role does a neutron serve in starting
a nuclear chain reaction and in keeping
it going?
b. Why must neutrons in a chain reaction
be controlled?
c. Why must there be a minimum mass of
material in order to sustain a chain reaction?

Katherine Mccandless
Katherine Mccandless
Numerade Educator
02:12

Problem 22

Under what conditions does fusion occur?

Matthew Lueckheide
Matthew Lueckheide
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02:45

Problem 23

Why do positron emission and electron
capture have the same effect on a nucleus?

Katherine Mccandless
Katherine Mccandless
Numerade Educator
01:47

Problem 24

Explain why nuclei that emit alpha particles,
such as americium-241, are safe to use in
smoke detectors.

Matthew Lueckheide
Matthew Lueckheide
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01:01

Problem 25

How does acute radiation exposure differ
from chronic radiation exposure?

Katherine Mccandless
Katherine Mccandless
Numerade Educator
03:44

Problem 26

Why do animals contain the same ratio of
carbon-14 to carbon-12 as plants do?

Matthew Lueckheide
Matthew Lueckheide
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01:41

Problem 27

What type of radioactive nuclide is injected
into a person who is about to undergo a
PET scan?

Katherine Mccandless
Katherine Mccandless
Numerade Educator
02:34

Problem 28

Describe how nuclear chemistry can be
used to detect an art forgery.

Matthew Lueckheide
Matthew Lueckheide
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01:08

Problem 29

What does the unit rem describe?

Katherine Mccandless
Katherine Mccandless
Numerade Educator
01:30

Problem 30

The decay of uranium-238 results in the
spontaneous ejection of an alpha particle.
Write the nuclear equation that describes
this process.

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
01:34

Problem 31

What type of radiation is emitted in the
decay described by the following equation?
$$_{19}^{43} \mathrm{K} \rightarrow_{20}^{43} \mathrm{Ca}+?$$

Katherine Mccandless
Katherine Mccandless
Numerade Educator
02:56

Problem 32

When a radon-222 nucleus decays, an alpha particle is emitted. Write the nuclear equation to show what happens when a radon-222 nucleus decays. What is the other product that forms?

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
08:47

Problem 33

One radioactive decay series that begins with
uranium-235 and ends with lead-207 shows
the partial sequence of emissions: alpha,
beta, alpha, beta, alpha, alpha, alpha, alpha,
beta, beta, and alpha. Write an equation for
each reaction in the series.

Katherine Mccandless
Katherine Mccandless
Numerade Educator
03:14

Problem 34

Balance the following nuclear reactions.
\begin{equation}a. \quad_{93}^{239} \mathrm{Np} \longrightarrow_{-1}^{0} e+?\end{equation}
\begin{equation}\begin{array}{l}{\text { b. }_{4}^{9} \mathrm{Be}+_{2}^{4} \mathrm{He} \longrightarrow ?} \\ {\text { c. } _{15}^{32} \mathrm{P}+? \longrightarrow_{15}^{33} \mathrm{P}}\end{array}\end{equation}
\begin{equation}d. _{92}^{236} \mathrm{U} \longrightarrow_{36}^{94} \mathrm{Kr}+?+3_{0}^{1} n\end{equation}

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
02:47

Problem 35

Complete and balance the following nuclear
equations:
\begin{equation}a. \quad_{75}^{187} \mathrm{Re}+? \longrightarrow_{75}^{188} \mathrm{Re}+_{1}^{1} \mathrm{H}\end{equation}
\begin{equation}b.\quad_{4}^{9} \mathrm{Be}+_{2}^{4} \mathrm{He} \longrightarrow ?+_{0}^{1} n
\end{equation}
\begin{equation}c.\quad_{11}^{22} \mathrm{Na}+? \longrightarrow_{10}^{22} \mathrm{Ne}\end{equation}

Katherine Mccandless
Katherine Mccandless
Numerade Educator
01:19

Problem 36

Write the nuclear equation for the release
of a positron by $_{54}^{117} \mathrm{Xe} .$

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
04:03

Problem 37

Copper-64 is used to study brain tumors.
Assume that the original mass of a sample
of copper-64 is 26.00 g. After 64 hours, all
that remains is 0.8125 g of copper-64. What
is the half-life of this radioactive isotope?

Anatole Borisov
Anatole Borisov
Numerade Educator
02:11

Problem 38

The half-life of thorium-234 is 24.10 days.
How many days until only one-sixteenth of
a 52.0 g sample of thorium-234 remains?

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
01:00

Problem 39

The half-life of carbon-14 is 5715 y. How long will it be until only half of the carbon-14 in a sample remains?

Katherine Mccandless
Katherine Mccandless
Numerade Educator
03:00

Problem 40

The half-life of one radon isotope is 3.8
days. If a sample of gas contains 4.38 g of
radon-222, how much radon will remain in
the sample after 15.2 days?

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
02:09

Problem 41

After 4797 y, how much of an original
0.450 g of radium-226 remains? The half-life
of radium-226 is 1599 y.

Katherine Mccandless
Katherine Mccandless
Numerade Educator
04:11

Problem 42

The half-life of cobalt--60 is 10.47 min. How
many milligrams of $\mathrm{Co}-60$ remain after
104.7 min if you start with 10.0 $\mathrm{mg}$ of $\mathrm{Co}-60$ ?

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
04:06

Problem 43

Calculate the neutron-proton ratios for the
following nuclides, and determine where
they lie in relation to the band of stability.
\begin{equation}a. _{92}^{235} \mathrm{U}\end{equation}
\begin{equation}b. _{8}^{16} \mathrm{O}\end{equation}
\begin{equation}c. _{26}^{56} \mathrm{Fe}\end{equation}
\begin{equation}c. _{60}^{156} \mathrm{Nd}\end{equation}

Katherine Mccandless
Katherine Mccandless
Numerade Educator
06:11

Problem 44

Calculate the binding energy per nucleon
of $_{92}^{238} \mathrm{U}$ in joules. The atomic mass of a $_{92}^{238} \mathrm{U}$
nucleus is 238.050784 amu.

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
01:16

Problem 45

The energy released by the formation of a nucleus of $_{26}^{56} \mathrm{U}$ is $7.89 \times 10^{-11} \mathrm{J}$ Einstein's equation, $E=m c^{2},$ to determine how much mass is lost (in kilograms) in this process.

Katherine Mccandless
Katherine Mccandless
Numerade Educator
01:53

Problem 46

What nuclear process is occuring in the sun
shown? Also, write a nuclear reaction that
describes this process.

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
01:59

Problem 47

The radiation given off by iodine-131 in the form of beta particles is used to treat cancer of the thyroid gland.Write the nuclear equation to describe the decay of an iodine-131 nucleus.

Katherine Mccandless
Katherine Mccandless
Numerade Educator
02:42

Problem 48

The parent nuclide of the thorium decay
series is $_{90}^{232}$ Th. The first four decays are as
follows: alpha emission, beta emission, beta
emission, and alpha emission. Write the
nuclear equations for this series of emissions.

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
01:29

Problem 49

The half-life of radium- $-224$ is 3.66 days.
What was the original mass of radium-224
if 0.0500 g remains after 7.32 days?

David Collins
David Collins
Numerade Educator
02:42

Problem 50

How many milligrams remain of a 15.0 $\mathrm{mg}$
sample of radium-226 after 6396 $\mathrm{y} ?$ The
half-life of this isotope is 1599 $\mathrm{y}$ .

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
02:45

Problem 51

The mass of a $_{3}^{7}$ Li atom is 7.01600 amu.
Calculate its mass defect.

Katherine Mccandless
Katherine Mccandless
Numerade Educator
01:14

Problem 52

Determine whether each of the following
nuclear reactions involves alpha decay, beta
decay, positron emission, or electron
capture.
\begin{equation}\begin{array}{l}{\text { a. }_{90}^{234} \mathrm{Th} \rightarrow_{-1}^{0} e+_{91}^{234} \mathrm{Pa}} \\ {\text { b. }_{92}^{238} \mathrm{U} \longrightarrow_{2}^{4} \mathrm{He}+_{90}^{234} \mathrm{Th}} \\ {\text { c. }_{8}^{15} \mathrm{O} \longrightarrow_{+1}^{0} e+_{7}^{15} \mathrm{N}}\end{array}\end{equation}

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
01:57

Problem 53

Uranium-238 decays through alpha decay
with a half-life of $4.46 \times 10^{9}$ y. How long
would it take for seven-eighths of a sample
of uranium- $-238$ to decay?.

Katherine Mccandless
Katherine Mccandless
Numerade Educator
00:59

Problem 54

Write the nuclear equation for the release
of an alpha particle by $_{70}^{157} \mathrm{Yb} .$

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
02:17

Problem 55

The half-life of iodine- $-131$ is 8.02 days. What
percentage of an iodine-131 sample will
remain after 40.2 days?

Katherine Mccandless
Katherine Mccandless
Numerade Educator
04:22

Problem 56

The mass of a $_{10}^{20} \mathrm{Ne}$ atom is 19.99244 amu.
Calculate its mass defect.

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
04:38

Problem 57

Calculate the nuclear binding energy of one
lithium-6 atom. The measured atomic mass
of lithium-6 is 6.015 amu.

Katherine Mccandless
Katherine Mccandless
Numerade Educator
00:53

Problem 58

Write the nuclear equation for the release
of a beta particle by $_{210}^{82} \mathrm{Pb} .$

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
01:31

Problem 59

The half-life of an element $X$ is 5.25 y. How
many days are required for one-fourth of a
given amount of $X$ to decay?

Katherine Mccandless
Katherine Mccandless
Numerade Educator
02:17

Problem 60

Complete the following nuclear reactions.
\begin{equation}a. _{5}^{12} \mathrm{B} \rightarrow_{6}^{12} \mathrm{C}+?\end{equation}
\begin{equation}b. _{89}^{225} \mathrm{Ac} \longrightarrow_{87}^{221} \mathrm{Fr}+?\end{equation}
\begin{equation}\mathbf{c.}_{28}^{63} \mathrm{Ni} \longrightarrow ?+_{-1}^{0} e\end{equation}
\begin{equation}\mathbf{d} \cdot_{83}^{212} \mathrm{Bi} \rightarrow ?+_{2}^{4} \mathrm{He}\end{equation}

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
01:57

Problem 61

Actinium-217 decays by releasing an alpha
particle. Write an equation for this decay
process, and determine what element is
formed.

Katherine Mccandless
Katherine Mccandless
Numerade Educator
02:47

Problem 62

Indicate if the following equations represent
fission reactions or fusion reactions.
\begin{equation}a. _{1}^{1} \mathrm{H}+_{1}^{2} \mathrm{H} \longrightarrow_{2}^{3} \mathrm{He}+\gamma\end{equation}
\begin{equation}b. _{0}^{1} n+_{92}^{235} \mathrm{U} \longrightarrow_{57}^{146} \mathrm{La}+_{35}^{87} \mathrm{Br}+3_{0}^{1} n\end{equation}
\begin{equation}c. _{10}^{21} \mathrm{Ne}+_{2}^{4} \mathrm{He} \longrightarrow_{12}^{24} \mathrm{Mg}+_{0}^{1} n\end{equation}
\begin{equation}d. _{82}^{208} \mathrm{Pb}+_{58}^{26} \mathrm{Fe} \longrightarrow_{108}^{265} \mathrm{Hs}+_{0}^{1} n\end{equation}

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
02:03

Problem 63

Predict whether the total mass of the 26
protons and neutrons that make up the iron
nucleus will be more, less, or equal to 55.845
amu, the mass of an iron atom from the
periodic table. If it is not equal, explain
why not.

Katherine Mccandless
Katherine Mccandless
Numerade Educator
01:31

Problem 64

A sample of francium- 212 will decay to one sixteenth its original amount after $80 \mathrm{~min}$. What is the half-life of francium-212?

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
01:37

Problem 65

Identify which of the four common types of
nuclear radiation (beta, neutron, alpha, or
gamma) correspond to the following
descriptions:
\begin{equation}\begin{array}{l}{\text { a. an electron }} \\ {\text { b. uncharged particle }} \\ {\text { c. can be stopped by a piece of paper }} \\ {\text { d. high-energy light }}\end{array}\end{equation}

Katherine Mccandless
Katherine Mccandless
Numerade Educator
01:08

Problem 66

Calculate the time required for three-
fourths of a sample of cesium-138 to decay
given that its half-life is 32.2 $\mathrm{min} .$

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
01:58

Problem 67

Calculate that half-life of cesium-135 if
seven-eighths of a sample decays in $6 \times 10^{6} \mathrm{y}$ .

Katherine Mccandless
Katherine Mccandless
Numerade Educator
02:35

Problem 68

An archaeologist discovers a wooden mask
whose carbon-14 to carbon-12 ratio is one-
sixteenth the ratio measured in a newly
fallen tree. How old does the wooden mask
seem to be, given this evidence?

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
01:39

Problem 69

The half-life of tritium, $_{1}^{3} \mathrm{H},$ is 12.3 $\mathrm{y} .$ How
long will it take for seven-eighths of the
sample to decay?

Katherine Mccandless
Katherine Mccandless
Numerade Educator
00:57

Problem 70

It takes about $10^{6}$ y for just half the samar-
ium-149 in nature to decay by alpha-particle
emission. Write the decay equation, and find
the isotope that is produced by the reaction.

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
01:27

Problem 71

Describe some of the similarities and differ-
ences between atomic electrons and beta
particles.

Katherine Mccandless
Katherine Mccandless
Numerade Educator
02:18

Problem 72

Medium-mass nuclei have larger binding
energies per nucleon than heavier nuclei do.
What can you conclude from this fact?

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
01:12

Problem 73

Why are elevated temperatures necessary
to initiate fusion reactions but not fission
reactions?

Katherine Mccandless
Katherine Mccandless
Numerade Educator
01:33

Problem 74

Why is the constant rate of decay of radioac-
tive nuclei so important in radioactive dating?

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
01:18

Problem 75

Why would someone working around radio-
active waste in a landfill use a radiation

monitor instead of a watch to determine
when the workday is over? At what point
would that person decide to stop working?

Katherine Mccandless
Katherine Mccandless
Numerade Educator
02:52

Problem 76

Explain why charged particles do not pene-
trate matter deeply.

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
02:09

Problem 77

Research some important historical findings
that have been validated through radioactive
dating. Report your findings to the class.

Katherine Mccandless
Katherine Mccandless
Numerade Educator
02:17

Problem 78

Design an experiment that illustrates the
concept of half-life.

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
04:02

Problem 79

Research and evaluate environmental issues
regarding the storage, containment, and
disposal of nuclear wastes.

Katherine Mccandless
Katherine Mccandless
Numerade Educator
04:16

Problem 80

Suppose you are an energy consultant who
has been asked to evaluate a proposal to
build a power plant in a remote area of the
desert. Research the requirements for each
of the following types of power plant:
nuclear-fission power plant, coal-burning
power plant, solar-energy farm. Decide
which of these power plants would be best
for its surroundings, and write a paragraph
supporting your decision.

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
01:30

Problem 81

Use the following terms to complete the
concept map below: critical mass, chain
reaction, nuclear fission, and nucleon.

Katherine Mccandless
Katherine Mccandless
Numerade Educator
02:29

Problem 82

Study the graph below, and answer the questions that follow.
For help in interpreting graphs, see Appendix B, "Study Skills for Chemistry."
Do stable nuclei that have N/Z numbers
approximately equal to 1 have small or
large atomic numbers?

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
01:00

Problem 83

Study the graph below, and answer the questions that follow.
For help in interpreting graphs, see Appendix $B$ , "Study Skills for Chemistry."
Do stable nuclei that have $N / Z$ numbers
approximately equal to 1.5 have small or
large atomic numbers?

Katherine Mccandless
Katherine Mccandless
Numerade Educator
00:30

Problem 84

Study the graph below, and answer the questions that follow.
For help in interpreting graphs, see Appendix $B,$ "Study Skills for Chemistry."
Calculate the $N / Z$ number for a nucleus $\mathrm{A}$
that has 70 neutrons and 50 protons.

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
01:02

Problem 85

Study the graph below, and answer the questions that follow.
For help in interpreting graphs, see Appendix $B,$ "Study Skills for Chemistry."
Calculate the $N / Z$ number for a nucleus $\mathrm{B}$
that has 90 neutrons and 60 protons.

Katherine Mccandless
Katherine Mccandless
Numerade Educator
01:08

Problem 86

Study the graph below, and answer the questions that follow.
For help in interpreting graphs, see Appendix $B,$ "Study Skills for Chemistry."
Does nucleus A or nucleus B have an $N / Z$
number closer to 1.5$?$

Matthew Lueckheide
Matthew Lueckheide
Numerade Educator
01:56

Problem 87

Calculating the Amount of Radioactive Material
The graphing calculator can run a program that graphs the relationship between the amount of radioactive material and elapsed time. Given the half-life of the radioactive material and the initial amount of material in grams, you will graph the relationship between the amount of radioactive material and the elapsed time. Then, with the elapsed time, you will trace the graph to calculate the amount of radioactive material.
Go to Appendix C. If you are using a TI-83
Plus, you can download the program RADIOACT and run the application as directed. If you are using another calculator, your teacher will provide you with key-strokes and data sets to use. After you have run the program, answer these questions.
a. Determine the amount of neptunium-235 left after 2.0 years, given the half-life of neptunium-235 is 1.08 years and the initial amount was 8.00 g.
b. Determine the amount of neptunium-235 left after 5.0 years, given the half-life of neptunium-235 is 1.08 years and the initial amount was 8.00 g.
c. Determine the amount of uranium-232 left after 100 years, given the half-life of uranium-232 is 69 years and the initial amount was 10.0 g.

Katherine Mccandless
Katherine Mccandless
Numerade Educator