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Schaum’s Outline of College Physics

Eugene Hecht

Chapter 42

Quantum Physics and Wave Mechanics - all with Video Answers

Educators


Chapter Questions

01:50

Problem 1

Show that the photons in a 1240 -nm infrared beam have energies of $1.00 \mathrm{eV}$
$$
\mathrm{E}=h f=\frac{h \mathrm{c}}{\lambda}=\frac{\left(6.63 \times 10^{-34} \mathrm{~J} \cdot \mathrm{s}\right)\left(2.998 \times 10^{8} \mathrm{~m} / \mathrm{s}\right)}{1240 \times 10^{-9} \mathrm{~m}}=1.602 \times 10^{-19} \mathrm{~J}=1.00 \mathrm{eV}
$$

Dominique Jan Tan
Dominique Jan Tan
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01:45

Problem 2

Compute the energy of a photon of blue light of wavelength 450 $\mathrm{nm} .$
$$
E=\frac{h \mathrm{c}}{\lambda}=\frac{\left(6.63 \times 10^{-34} \mathrm{~J} \cdot \mathrm{s}\right)\left(2.998 \times 10^{8} \mathrm{~m} / \mathrm{s}\right)}{450 \times 10^{-9} \mathrm{~m}}=4.42 \times 10^{-19} \mathrm{~J}=2.76 \mathrm{eV}
$$

Dominique Jan Tan
Dominique Jan Tan
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02:58

Problem 3

To break a chemical bond in the molecules of human skin and thus cause sunburn, a photon energy of about $3.50 \mathrm{eV}$ is required. To what wavelength does this correspond?
$$
\lambda=\frac{h \mathrm{c}}{\mathrm{E}}=\frac{\left(6.63 \times 10^{-34} \mathrm{~J} \cdot \mathrm{s}\right)\left(2.998 \times 10^{8} \mathrm{~m} / \mathrm{s}\right)}{(3.50 \mathrm{eV})\left(1.602 \times 10^{-19} \mathrm{~J} / \mathrm{eV}\right)}=354 \mathrm{~nm}
$$
Ultraviolet radiation causes sunburn.

Dominique Jan Tan
Dominique Jan Tan
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02:49

Problem 4

The work function of sodium metal is $2.3 \mathrm{eV}$. What is the longestwavelength light that can cause photoelectron emission from sodium?
At threshold, the photon energy just equals the energy required to tear the electron loose from the metal. In other words, the
electron's $\mathrm{KE}$ is zero and so $h f=\varphi$. Since $f=c / \lambda$
$$
\begin{array}{c}
\phi=\frac{h \mathrm{c}}{\lambda} \\
(2.3 \mathrm{eV})\left(\frac{\left(1.602 \times 10^{-19} \mathrm{~J}\right.}{1.00 \mathrm{eV}}\right)=\frac{\left(6.63 \times 10^{-34} \mathrm{~J} \cdot \mathrm{s}\right)\left(2.998 \times 10^{8} \mathrm{~m} / \mathrm{s}\right)}{\lambda} \\
\lambda=5.4 \times 10^{-7} \mathrm{~m}
\end{array}
$$

Dominique Jan Tan
Dominique Jan Tan
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03:17

Problem 5

What potential difference must be applied to stop the fastest photoelectrons emitted by a nickel surface under the action of ultraviolet light of wavelength $200 \mathrm{~nm}$ ? The work function of nickel is $5.01 \mathrm{eV}$.
$$
\mathrm{E}=\frac{h \mathrm{c}}{\lambda}=\frac{\left(6.63 \times 10^{-34} \mathrm{~J} \cdot \mathrm{s}\right)\left(2.998 \times 10^{8} \mathrm{~m} / \mathrm{s}\right)}{2000 \times 10^{-10} \mathrm{~m}}=9.95 \times 10^{-19} \mathrm{~J}=6.21 \mathrm{eV}
$$
Then, from the photoelectric equation, the energy of the fastest emitted electron is
$$
6.21 \mathrm{eV}-5.01 \mathrm{eV}=1.20 \mathrm{eV}
$$
Hence, a negative retarding potential of $1.20 \mathrm{~V}$ is required. This is the stopping potential.

Dominique Jan Tan
Dominique Jan Tan
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03:33

Problem 6

Will photoelectrons be emitted by a metal surface, of work function $4.4 \mathrm{eV}$, when illuminated by visible light?

As in $\underline{\text { Problem } 42.4}$, the released-electron's $\mathrm{KE}=0$ and so
$$
\text { eshold } \lambda=\frac{h \mathrm{c}}{\phi}=\frac{\left(6.63 \times 10^{-34} \mathrm{~J} \cdot \mathrm{s}\right)\left(2.998 \times 10^{8} \mathrm{~m} / \mathrm{s}\right)}{4.4\left(1.602 \times 10^{-19}\right) \mathrm{J}}=282 \mathrm{~nm}
$$
Hence, visible light $(350 \mathrm{~nm}$ to $700 \mathrm{~nm})$ cannot eject photoelectrons from copper.

Dominique Jan Tan
Dominique Jan Tan
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03:43

Problem 7

A beam $(\lambda=633 \mathrm{~nm})$ from a typical laser designed for student use has an intensity of $3.0 \mathrm{~mW}$. How many photons pass a given point in the beam each second?

The energy that is carried past the point each second is $0.0030 \mathrm{~J}$. Because the energy per photon is $h c / \lambda$, which works out to be $3.14$ $\times 10^{-19} \mathrm{~J}$, the number of photons passing the point per second is
$$
\text { Number } / \mathrm{s}=\frac{0.0030 \mathrm{~J} / \mathrm{s}}{3.14 \times 10^{-19} \mathrm{~J} / \text { photon }}=9.5 \times 10^{15} \text { photon } / \mathrm{s}
$$

Dominique Jan Tan
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03:33

Problem 8

In a process called pair production, a photon is transformed into an electron and a positron. A positron has the same mass $\left(m_{e}\right)$ as the electron, but its charge is $+e$. To three significant figures, what is the minimum energy a photon can have if this process is to occur? What is the corresponding wavelength?
The electron-positron pair will come into existence moving with some minimum amount of KE. The particles will separate, and as they do they will slow down. When far apart each will have a mass of $9.11 \times 10^{-31} \mathrm{~kg} .$ In effect, KE goes into $\mathrm{PE}$, which is manifested as mass.
Thus, the minimum energy photon at the start of the process must have the energy equivalent of the free-particle mass of the pair at the end of the process. Hence,

Emily Anderson
Emily Anderson
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04:47

Problem 9

What wavelength must electromagnetic radiation have if a photon in the beam is to have the same momentum as an electron moving with a speed of $2.000 \times 10^{5} \mathrm{~m} / \mathrm{s}$ ?
The requirement is that $(m v)_{\text {electron }}=(h / \lambda)_{\text {photon }}$. From this,
$$
\lambda=\frac{h}{m v}=\frac{6.63 \times 10^{-34} \mathrm{~J} \cdot \mathrm{s}}{\left(9.11 \times 10^{-31} \mathrm{~kg}\right)\left(2.00 \times 10^{5} \mathrm{~m} / \mathrm{s}\right)}=3.64 \mathrm{~nm}
$$
This wavelength is in the X-ray region.

Emily Anderson
Emily Anderson
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02:13

Problem 10

Suppose that a 3.64-nm photon moving in the $+x$ -direction collides head-on with a $2 \times 10^{5} \mathrm{~m} / \mathrm{s}$ electron moving in the $-x$ direction. If the collision is perfectly elastic, find the conditions after collision.
From the law of conservation of momentum,
Momentum before = Momentum after
$$
\frac{h}{\lambda_{0}}-m v_{0}=\frac{h}{\lambda}-m v
$$
But, from $\underline{\text { Problem } 42.9,} h / \lambda_{0}=m u$ in this case. Hence, $h / \lambda=m v$. Also, for a perfectly elastic collision,
$$
\begin{array}{l}
\text { KE before }=\text { KE after } \\
\frac{h c}{\lambda_{0}}+\frac{1}{2} m v_{0}^{2}=\frac{h c}{\lambda}+\frac{1}{2} m v^{2}
\end{array}
$$
Using the facts that $h / \lambda_{0}=m v_{0}$ and $h / \lambda=m v$, we find
$$
v_{0}\left(\mathrm{c}+\frac{1}{2} v_{0}\right)=v\left(\mathrm{c}+\frac{1}{2} v\right)
$$
Therefore, $v=\mathrm{u}_{0}$ and the electron moves in the $+\chi$ -direction with its original speed. Because $h / \lambda=m v=m u_{0}$, the photon also "rebounds," and with its original wavelength.

Suzanne W.
Suzanne W.
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02:50

Problem 11

A photon $(\lambda=0.400 \mathrm{~nm})$ strikes an electron at rest and rebounds at an angle of $150^{\circ}$ to its original direction. Find the speed and wavelength of the photon after the collision.
The speed of a photon is always the speed of light in vacuum, $\mathrm{c}$. To obtain the wavelength after collision, use the equation for the
Compton Effect:
$$
\begin{array}{l}
\lambda_{s}=\lambda_{i}+\frac{h}{m_{e} c}(1-\cos \theta) \\
\lambda_{s}=4.00 \times 10^{-10} \mathrm{~m}+\frac{6.63 \times 10^{-34} \mathrm{~J} \cdot \mathrm{s}}{\left(9.11 \times 10^{-31} \mathrm{~kg}\right)\left(2.998 \times 10^{8} \mathrm{~m} / \mathrm{s}\right)}\left(1-\cos 150^{\circ}\right) \\
\lambda_{s}=4.00 \times 10^{-10} \mathrm{~m}+\left(2.43 \times 10^{-12} \mathrm{~m}\right)(1+0.866)=0.405 \mathrm{~nm}
\end{array}
$$

Brandy Heflin
Brandy Heflin
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05:04

Problem 12

What is the de Broglie wavelength for a particle moving with speed $2.0 \times 10^{6} \mathrm{~m} / \mathrm{s}$ if the particle is $(a)$ an electron, $(b)$ a proton, and $(c)$ a $0.20$ -kg ball?
We make use of the definition of the de Broglie wavelength:
$$
\lambda=\frac{h}{m v}=\frac{6.63 \times 10^{-34} \mathrm{~J} \cdot \mathrm{s}}{m\left(2.0 \times 10^{6} \mathrm{~m} / \mathrm{s}\right)}=\frac{3.31 \times 10^{-40} \mathrm{~m} \cdot \mathrm{kg}}{m}
$$
Substituting the required values for $m$, one finds that the wavelength is $3.6 \times 10^{-10} \mathrm{~m}$ for the electron, $2.0 \times 10^{-13} \mathrm{~m}$ for the proton, and $1.7 \times 10^{-39} \mathrm{~m}$ for the $0.20$ -kg ball.

Emily Anderson
Emily Anderson
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03:45

Problem 13

An electron falls from rest through a potential difference of 100 $\mathrm{V}$. What is its de Broglie wavelength?
Its speed will still be far below c, so relativistic effects can be ignored. The KE gained, $\frac{1}{2} m v^{2}$, equals the electrical PE lost, $V q$. Therefore,
$$
\begin{array}{l}
v=\sqrt{\frac{2 V q}{m}}=\sqrt{\frac{2\left(00 \mathrm{~V} \times 1.60 \times 10^{-19} \mathrm{C}\right)}{9.11 \times 10^{-11} \mathrm{~kg}}}=5.927 \times 10^{6} \mathrm{~m} / \mathrm{s} \\
\lambda=\frac{h}{m v}=\frac{6.626 \times 10^{-34} \mathrm{~J} \cdot \mathrm{s}}{\left(9.11 \times 10^{-35} \mathrm{~kg}\right)\left(5.927 \times 10^{6} \mathrm{~m} / \mathrm{s}\right)}=0.123 \mathrm{~nm}
\end{array}
$$

Emily Anderson
Emily Anderson
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03:24

Problem 14

What potential difference is required in an electron microscope to give electrons a wavelength of $0.500 \AA$ ?
$$
\text { E of electron }=\frac{1}{2} m v^{2}=\frac{1}{2} m\left(\frac{h}{m \lambda}\right)^{2}=\frac{h^{2}}{2 m \lambda^{2}}
$$
where use has been made of the de Broglie relation, $\lambda=\mathrm{h} / \mathrm{mv}$ Substitution of the known values gives the $\mathrm{KE}$ as $9.66 \times 10^{-17} \mathrm{~J}$.
But $\mathrm{KE}=V q$, and $\mathrm{so}$
$$
V=\frac{\mathrm{KE}}{q}=\frac{9.66 \times 10^{-17} \mathrm{~J}}{1.60 \times 10^{-19} \mathrm{C}}=600 \mathrm{~V}
$$

Emily Anderson
Emily Anderson
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04:55

Problem 15

By definition, a thermal neutron is a free neutron in a neutron gas at about $20{ }^{\circ} \mathrm{C}$ ( $293 \mathrm{~K}$ ). What are the $\mathrm{KE}$ and wavelength of such a neutron?

From Chapter 17 , the thermal energy of a gas molecule is $3 k T / 2$, where $k$ is Boltzmann's constant $\left(1.38 \times 10^{-23} \mathrm{~J} / \mathrm{K}\right)$. Then
$$
\mathrm{KE}=\frac{3}{2} k T=6.07 \times 10^{-21} \mathrm{~J}
$$
This is a nonrelativistic situation for which we can write
the

Emily Anderson
Emily Anderson
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06:30

Problem 16

[I] Find the pressure exerted on a surface by the photon beam of Problem $42.7$ if the cross-sectional area of the beam is $3.0 \mathrm{~mm}^{2}$. Assume perfect reflection at normal incidence.
Each photon has a momentum
$$
p=\frac{h}{\lambda}=\frac{6.63 \times 10^{-34} \mathrm{~J} \cdot \mathrm{s}}{633 \times 10^{-9} \mathrm{~m}}=1.05 \times 10^{-27} \mathrm{~kg} \cdot \mathrm{m} / \mathrm{s}
$$
When a photon reflects, it changes momentum from $+p$ to $-p, a$ total change of $2 p$. Since (from $\underline{\text { Problem } 42.7}$ ) $9.5 \times 10^{15}$ photons strike the surface each second,
Momentum change/s $=\left(9.5 \times 10^{15} / \mathrm{s}\right)(2)\left(1.05 \times 10^{-27} \mathrm{~kg} \cdot \mathrm{m} / \mathrm{s}^{2}\right)=$
$2.0 \times 10^{-11} \mathrm{~kg} \cdot \mathrm{m} / \mathrm{s}^{2}$
From the impulse equation (Chapter 8),
Impulse $=F t=$ Change in momentum
haxy $\xi=$ Monentum change $/ \mathrm{s}=1.99 \times 10^{-11} \mathrm{~kg} \cdot \mathrm{m} / / \mathrm{s}$
$=\frac{F}{A}=\frac{1.99 \times 10^{-11} \mathrm{~kg} \cdot \mathrm{m} / \mathrm{s}^{2}}{3.0 \times 10^{-0} \mathrm{~m}^{2}}=6.6 \times 10^{-6} \mathrm{~N} / \mathrm{m}^{2}$

Emily Anderson
Emily Anderson
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08:45

Problem 17

I] A particle of mass $m$ is confined to a narrow tube of length $L$. Find $(a)$ the wavelengths of the de Broglie waves which will resonate in the tube, (b) the corresponding particle momenta, and
(c) the corresponding energies. (d) Evaluate the energies for an electron in a tube with $L=0.50 \mathrm{~nm}$.
(a) The de Broglie waves will resonate with a node at each end of the tube because the ends are impervious. A few of the possible resonance forms are shown in Fig. $42-1$. They indicate that, for resonance, $L=\frac{1}{2} \lambda_{1}, 2\left(\frac{1}{2} \lambda_{2}\right), 3\left(\frac{1}{2} \lambda_{3}\right), \ldots, n\left(\frac{1}{2} \lambda_{n}\right), \ldots$ or
(b) Because the de Broglie wavelengths are $\lambda_{\mathrm{n}}=h / p_{n}$, the resonance momenta are
$$
p_{n}=\frac{n h}{2 L} \quad n=1,2,3, \ldots
$$ (c) As shown in Problem 42.15, $p^{2}=(2 m)(\mathrm{KE})$, and so
$$
(\mathrm{KE})_{n}=\frac{n^{2} h^{2}}{8 L^{2} m} \quad n=1,2,3, \ldots
$$
Notice that the particle can assume only certain discrete energies. The energies are quantized.
(d) With $m=9.1 \times 10^{-31} \mathrm{~kg}$ and $L=5.0 \times 10^{-10} \mathrm{~m}$, substitution yields
$$
(\mathrm{KE})_{n}=2.4 \times 10^{-19} n^{2} \mathrm{~J}=1.5 n^{2} \mathrm{eV}
$$

Daniel Sneed
Daniel Sneed
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03:21

Problem 18

II] A particle of mass $m$ is confined to a circular orbit with radius $R$. For resonance of its de Broglie wave on this orbit, what energies can the particle have? Determine the KE for an electron with $R=$ $0.50 \mathrm{~nm}$.
To resonate on a circular orbit, a wave must circle back on itself in such a way that crest falls upon crest and trough falls upon trough. One resonance possibility (for an orbit circumference that is four wavelengths long) is shown in $\underline{\text { Fig. } 42-2 . \text { In general, resonance }}$ occurs when the circumference is $n$ wavelengths long, where $n=$ $1,2,3, \ldots .$ For such a de Broglie wave
$$
n \lambda_{n}=2 \pi R \quad \text { and } \quad p_{n}=\frac{h}{\lambda_{n}}=\frac{n h}{2 \pi R}
$$ Fig. $42-2$
As in Problem $42.17$,
$$
(\mathrm{KE})_{n}=\frac{p_{n}^{2}}{2 m}=\frac{n^{2} h^{2}}{8 \pi^{2} R^{2} m}
$$
The energies are obviously quantized. Placing in the values requested leads to
$$
(\mathrm{KE})_{n}=2.4 \times 10^{-20} n^{2} \mathrm{~J}=0.15 n^{2} \mathrm{eV}
$$

Linda Winkler
Linda Winkler
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01:23

Problem 19

[I] If you double the frequency of a photon, what happens to its energy? Explain your answer.

Dominique Jan Tan
Dominique Jan Tan
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01:19

Problem 20

If you double the wavelength of a photon, what happens to its energy? Explain your answer.

Dominique Jan Tan
Dominique Jan Tan
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02:12

Problem 21

Show that Planck's constant, $h=6.626 \times 10^{-34}$ J.s, can be expressed as $4.136 \times 10^{-15}$ eV.s. [Hint: Remember that the $\mathrm{eV}$ involves the charge on the electron.]

Dominique Jan Tan
Dominique Jan Tan
Numerade Educator
03:53

Problem 22

Show that $h \mathrm{c}=1240 \mathrm{eV} \cdot \mathrm{nm} .$ This will be useful when we work with $\mathrm{E}=h c / \lambda$. [Hint: Study the previous problem. Use $c$ in $\mathrm{nm} / \mathrm{s}$ remembering that there are a lot more nanometers per second than meters per second.]

Dominique Jan Tan
Dominique Jan Tan
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02:29

Problem 23

What is the energy of a photon in $\mathrm{eV}$ if it has a wavelength of 700 nm? [Hint: Study the last two problems.]

Dominique Jan Tan
Dominique Jan Tan
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01:41

Problem 24

Determine the energy in joules of a photon that has a wavelength of $589.3 \mathrm{~nm}$ at the center of the sodium doublet.

Dominique Jan Tan
Dominique Jan Tan
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02:37

Problem 25

A photon has an energy of $2.0 \mathrm{eV}$. Determine its wavelength.

Dominique Jan Tan
Dominique Jan Tan
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02:17

Problem 26

A photon has an energy of $4.0 \mathrm{eV}$. Determine its frequency
expressed in terahertz. [Hint: Study Problem $41.21 .1$

Dominique Jan Tan
Dominique Jan Tan
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01:45

Problem 27

Determine the momentum of a photon having a frequency of $410.0$ $\mathrm{THz}$

Dominique Jan Tan
Dominique Jan Tan
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02:11

Problem 28

What is the wavelength of light in which the photons have an energy of $600 \mathrm{eV}$ ?

Dominique Jan Tan
Dominique Jan Tan
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02:10

Problem 29

What must be the wavelength of a photon if it is to have the same momentum as an electron traveling at $2.2 \mathrm{~km} / \mathrm{s}$ ?

Dominique Jan Tan
Dominique Jan Tan
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03:19

Problem 30

What is the energy of the least energetic photon that can result in photoemission from a lead target? [Hint: Study Table $42-1 .]$

Emily Anderson
Emily Anderson
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05:28

Problem 31

What is the wavelength of the least energetic photon that can result in photoemission from a iron target? [Hint: Study Table 42-1.]

Emily Anderson
Emily Anderson
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03:02

Problem 32

A certain sodium lamp radiates $20 \mathrm{~W}$ of yellow light $(\lambda=589 \mathrm{~nm})$. How many photons of the yellow light are emitted from the lamp each second?

Dominique Jan Tan
Dominique Jan Tan
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01:31

Problem 33

What is the work function of sodium metal if the photoelectric threshold wavelength is $680 \mathrm{~nm}$ ?

Dominique Jan Tan
Dominique Jan Tan
Numerade Educator
05:28

Problem 34

Determine the maximum KE of photoelectrons ejected from a potassium surface by ultraviolet radiation of wavelength $200 \mathrm{~nm}$. What retarding potential difference is required to stop the emission of electrons? The photoelectric threshold wavelength for potassium is $440 \mathrm{~nm}$.

Emily Anderson
Emily Anderson
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05:31

Problem 35

With what speed will the fastest photoelectrons be emitted from a surface whose threshold wavelength is $600 \mathrm{~nm}$, when the surface is illuminated with light of wavelength $4 \times 10^{-7} \mathrm{~m} ?$

Emily Anderson
Emily Anderson
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07:10

Problem 36

Electrons with a maximum KE of $3.00 \mathrm{eV}$ are ejected from a metal surface by ultraviolet radiation of wavelength $150 \mathrm{~nm}$. Determine the work function of the metal, the threshold wavelength of the metal, and the retarding potential difference required to stop the emission of electrons.

Emily Anderson
Emily Anderson
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02:38

Problem 37

What are the speed and momentum of a 500 -nm photon?

Emily Anderson
Emily Anderson
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04:01

Problem 38

An X-ray beam with a wavelength of exactly $5.00 \times 10^{-14} \mathrm{~m}$ strikes a proton that is at rest $\left(m=1.67 \times 10^{-27} \mathrm{~kg}\right)$. If the X-rays are scattered through an angle of $110^{\circ}$, what is the wavelength of the scattered X-rays?

Emily Anderson
Emily Anderson
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05:13

Problem 39

A photon produces an electron and a positron, each of which has a kinetic energy of $220 \mathrm{keV}$ even when they are separated by a great distance. Find the energy and wavelength of the photon.

Emily Anderson
Emily Anderson
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04:45

Problem 40

Show that the de Broglie wavelength of an electron accelerated from rest through a potential difference of $V$ volts is $1.228 / \sqrt{V} \mathrm{~nm} .$ Ignore relativistic effects and take a look at Problem $42.13 .$

Emily Anderson
Emily Anderson
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04:57

Problem 41

Compute the de Broglie wavelength of an electron that has been accelerated through a potential difference of $9.0 \mathrm{kV}$. Ignore relativistic effects.

Emily Anderson
Emily Anderson
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04:37

Problem 42

What is the de Broglie wavelength of an electron that has been accelerated through a potential difference of $1.0 \mathrm{MV} ?$ (You must use the relativistic mass and energy expressions at this high energy.)

Abid Hussain
Abid Hussain
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01:46

Problem 43

It is proposed to send a beam of electrons through a diffraction grating. The electrons have a speed of $400 \mathrm{~m} / \mathrm{s}$. How large must the distance between slits be if a strong beam of electrons is to emerge at an angle of $25^{\circ}$ to the straight-through beam?

Narayan Hari
Narayan Hari
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