A simple pendulum is vibrating with an angu amplitude of $90^{\circ}$ as shown in the figure. For what va of $\alpha$, the acceleration is directed horizontally?
(a) 0
(b) $90^{\circ}$
(c) $\cos ^{-1}\left(\frac{1}{\sqrt{3}}\right)$
(d) $\sin ^{-1}\left(\frac{1}{\sqrt{3}}\right)$