Question
$$\begin{aligned}\Delta S=\frac{q_{m}}{T_{1}}+c \ln \frac{T_{2}}{T}+\frac{q_{v}}{T_{2}} & \\&=\frac{333}{273}+4 \cdot 18 \ln \frac{373}{283} \sim 8.56 \mathrm{~J} /{ }^{\circ} \mathrm{K}\end{aligned}$$
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$$ \begin{gathered} \Delta S=\int_{T_{1}}^{T_{2}} m c \frac{d T}{T}+\frac{m q}{T_{2}} \simeq m\left(c \ln \frac{T_{2}}{T_{1}}+\frac{q}{T_{2}}\right) \\ =10^{3}\left(4 \cdot 18 \ln \frac{373}{283}+\frac{2250}{373}\right)=7 \cdot 2 \mathrm{~kJ} / \mathrm{K} \end{gathered} $$
Thermodynamics And Molecular Physics
Phase Transformations
$$ \begin{aligned} &\Delta S=-\frac{m q_{1}}{T_{2}}-m c \ln \frac{T_{2}}{T_{1}}+\frac{M q_{i c e}}{T_{1}} \\ &\text { where } \quad M q_{i c e}=m\left(q_{2}+c\left(T_{2}-T_{1}\right)\right) \\ &=m q_{2}\left(\frac{1}{T_{1}}-\frac{1}{T_{2}}\right)+m c\left(\frac{T_{2}}{T_{1}}-1-\frac{T_{2}}{T_{1}}\right) \\ &=0.2245+0.2564 \sim 0.48 \mathrm{~J} / \mathrm{K} \end{aligned} $$
Given the values of $\Delta H_{\mathrm{rm}}^{\circ}, \Delta S_{\mathrm{rm}}^{\circ},$ and $T,$ determine $\Delta S_{\mathrm{univ}}$ and predictwhether each reaction is spontaneous. $ a.\quad \Delta H_{\mathrm{rxn}}^{\circ}=+115 \mathrm{k} J ; \quad \Delta S_{\mathrm{mn}}^{\circ}=-263 \mathrm{J} \quad {K} T=298 \mathrm{K} $ $ b.\quad \Delta H_{\mathrm{rxn}}^{\circ}= - 115 \mathrm{k} J ; \quad \Delta S_{\mathrm{mn}}^{\circ}=+263 \mathrm{J} \quad {K} T=298 \mathrm{K} $ $ c.\quad \Delta H_{\mathrm{rxn}}^{\circ}= - 115 \mathrm{k} J ; \quad \Delta S_{\mathrm{mn}}^{\circ}=-263 \mathrm{J} \quad {K} T=298 \mathrm{K} $ $ c.\quad \Delta H_{\mathrm{rxn}}^{\circ}= - 115 \mathrm{k} J ; \quad \Delta S_{\mathrm{mn}}^{\circ}=-263 \mathrm{J} \quad {K} T=615 \mathrm{K} $
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