For each of the reactions listed, determine the mole ratio of reactants that produces the maximum amount of precipitate. Be sure to balance the equations.
a. $\operatorname{AgNO}_{3}(a q)+\operatorname{NaCl}(a q) \longrightarrow \operatorname{AgCl}(s)+\operatorname{NaNO}_{3}(a q)$
b. $\mathrm{Cu}\left(\mathrm{NO}_{3}\right)_{2}(a q)+\mathrm{K}_{2} \mathrm{CO}_{3}(a q) \longrightarrow \mathrm{CuCO}_{3}(s)+\mathrm{KNO}_{3}(a q)$
c. $\mathrm{ZnCl}_{2}(a q)+\mathrm{NaOH}(a q) \longrightarrow \mathrm{Zn}(\mathrm{OH})_{2}(s)+\mathrm{NaCl}(a q)$
d. $\mathrm{CaCl}_{2}(a q)+\mathrm{Na}_{2} \mathrm{C}_{2} \mathrm{O}_{4}(a q) \longrightarrow \mathrm{CaC}_{2} \mathrm{O}_{4}(s)+\mathrm{NaCl}(a q)$